(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane

Base Information

• Chemical Name: (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane
• CAS No.: 162088-69-9
• Molecular Formula: C₃₆H₇₀BrClGeSi₆
• Molecular Weight: 859.412

Synonyms:(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane

Chemical Property of (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane

Chemical Property:

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Technology Process of (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane

There total 1 articles about (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

germaniumtetrachloride (10038-98-9) + 1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene (115160-05-9) + 2-mesitylmagnesium bromide (2633-66-1) → (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane (162088-69-9)

Guidance literature:

With t-BuLi; NH₄Cl; In tetrahydrofuran; pentane; Ar-atmosphere; stirring (-78°C, 10 min), GeCl4 addn. (-78°C), Grignard reagent addn. (room temp.), stirring (10 h), NH4Cl soln. (aq) addn.; concg. (reduced pressure), CHCl3 and HCl addn., extg. (CHCl3), drying (MgSO4), evapn. (reduced pressure), repptn. (CH2Cl2 / EtOH, room temp.);

DOI:10.1021/om00002a055

Reference yield: 79.0%

sulfur (10544-50-0) + (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane (162088-69-9) → 5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-5-mesityl-1,2,3,4,5-tetrathiagermolane (135139-69-4)

Guidance literature:

With t-BuLi; In tetrahydrofuran; pentane; Ar-atmosphere; stirring (-78°C, 5 min), S8 addn., refluxing (10 h); evapn. (reduced pressure), chromy. (SiO2, hexane), recrystn. (CH2Cl2 / EtOH, room temp.); elem. anal.;

DOI:10.1021/om00002a055

Reference yield: 72.0%

lithium aluminium tetrahydride (16853-85-3) + (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane (162088-69-9) → (mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrogermane (135139-78-5)

Guidance literature:

With NH₄Cl; In tetrahydrofuran; water; Ar-atmosphere; refluxing (10 h), NH4Cl soln. (aq) addn.; washing (HCl soln.), extg. (CHCl3), drying (MgSO4), evapn. (reduced pressure), repptn. (CH2Cl2 / EtOH, room temp.); elem. anal.;

DOI:10.1021/om00002a055

upstream raw materials:

germaniumtetrachloride

1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene

2-mesitylmagnesium bromide

Downstream raw materials:

5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-5-mesityl-1,2,3,4,5-tetrathiagermolane

(mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrogermane

(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)hydroxy(mesityl)(methylthio)germane

[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](hyroxy)(mercapto)(mesityl)germane

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