1L-(1,2,4/3)-1,2,3,4-tetra-O-benzyl-1-C-(benzyloxymethyl)-5-cyclohexen-1,2,3,4-tetrol

Base Information

Chemical Name:1L-(1,2,4/3)-1,2,3,4-tetra-O-benzyl-1-C-(benzyloxymethyl)-5-cyclohexen-1,2,3,4-tetrol
CAS No.:106988-93-6
Molecular Formula:C₄₂H₄₂O₅
Molecular Weight:626.792
Hs Code.:

Synonyms:1L-(1,2,4/3)-1,2,3,4-tetra-O-benzyl-1-C-(benzyloxymethyl)-5-cyclohexen-1,2,3,4-tetrol

Suppliers and Price of 1L-(1,2,4/3)-1,2,3,4-tetra-O-benzyl-1-C-(benzyloxymethyl)-5-cyclohexen-1,2,3,4-tetrol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1L-(1,2,4/3)-1,2,3,4-tetra-O-benzyl-1-C-(benzyloxymethyl)-5-cyclohexen-1,2,3,4-tetrol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1L-(1,2,4/3)-1,2,3,4-tetra-O-benzyl-1-C-(benzyloxymethyl)-5-cyclohexen-1,2,3,4-tetrol

There total 6 articles about 1L-(1,2,4/3)-1,2,3,4-tetra-O-benzyl-1-C-(benzyloxymethyl)-5-cyclohexen-1,2,3,4-tetrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 100-39-0
benzyl bromide

: 227930-72-5,1219194-46-3
(1D)-(1,3,4/2)-1,2,3-tri-O-benzyl-4-C-[(benzyloxy)methyl]cyclohex-5-ene-1,2,3,4-tetrol

: 106988-93-6
1L-(1,2,4/3)-1,2,3,4-tetra-O-benzyl-1-C-(benzyloxymethyl)-5-cyclohexen-1,2,3,4-tetrol

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 20 ℃; for 3.5h;
DOI:10.1002/(SICI)1522-2675(19990505)82:5<645::AID-HLCA645>3.0.CO;2-K

Reference yield: 60.0%

: 100-39-0
benzyl bromide

: 106988-92-5
1L-(1,2,4/3)-2,3,4-tri-O-benzyl-1-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol

: 106988-93-6
1L-(1,2,4/3)-1,2,3,4-tetra-O-benzyl-1-C-(benzyloxymethyl)-5-cyclohexen-1,2,3,4-tetrol

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 2h;
DOI:10.1002/jlac.198719870350

Reference yield:

: 110205-68-0
1,3,4,5-tetra-O-benzyl-6,7-dideoxy-L-xylo-hept-6-en-2-ulose

: 106988-93-6
1L-(1,2,4/3)-1,2,3,4-tetra-O-benzyl-1-C-(benzyloxymethyl)-5-cyclohexen-1,2,3,4-tetrol

Guidance literature:: Multi-step reaction with 3 steps

1: tetrahydrofuran / 0.75 h / -78 °C

2: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 168 h / 20 °C

3: sodium hydride / N,N-dimethyl-formamide / 3.5 h / 20 °C

With sodium hydride; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; 1: Grignard reaction / 2: Cyclization / 3: Etherification;
DOI:10.1002/(SICI)1522-2675(19990505)82:5<645::AID-HLCA645>3.0.CO;2-K