C₁₄H₁₈O₄S

Base Information

Chemical Name:C₁₄H₁₈O₄S
CAS No.:1290137-22-2
Molecular Formula:C₁₄H₁₈O₄S
Molecular Weight:282.361
Hs Code.:

C<sub>14</sub>H<sub>18</sub>O<sub>4</sub>S

Synonyms:C₁₄H₁₈O₄S

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₁₄H₁₈O₄S

Chemical Property:

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Technology Process of C₁₄H₁₈O₄S

There total 1 articles about C₁₄H₁₈O₄S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 110567-21-0
(1S,2R)-2-(benzyloxymethyl)-1-hydroxy-3-cyclopentene

: 124-63-0
methanesulfonyl chloride

: 1290137-22-2
C₁₄H₁₈O₄S

Guidance literature:: With triethylamine; In tetrahydrofuran; for 1h;
DOI:10.1002/ejoc.201001473

Reference yield: 82.0%

: 1290137-22-2
C₁₄H₁₈O₄S

: 1290137-23-3
(1S,2S,3S,4R)-2-(benzyloxymethyl)-3,4-dihydroxycyclopentyl methanesulfonate

: C₁₄H₂₀O₆S

Guidance literature:: With AD-mix β; In water; tert-butyl alcohol; at 0 ℃; for 12h; optical yield given as %de;
DOI:10.1002/ejoc.201001473

Reference yield:

: 1290137-22-2
C₁₄H₁₈O₄S

: 1146288-96-1
5'-O-benzyl-L-carba-ribothymidine

Guidance literature:: Multi-step reaction with 6 steps

1.1: AD-mix β / water; tert-butyl alcohol / 12 h / 0 °C

2.1: toluene-4-sulfonic acid / acetone / 4 h / 20 °C

3.1: potassium tert-butylate / N,N-dimethyl-formamide / 1 h / Reflux

4.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

4.2: oxone / 6 h / 0 °C

5.1: di-isopropyl azodicarboxylate; triphenylphosphine / diethyl ether / 0.5 h / 0 °C / Inert atmosphere

5.2: 0 - 20 °C / Inert atmosphere

5.3: 6 h / 20 °C / Inert atmosphere

6.1: di-isopropyl azodicarboxylate; triphenylphosphine / acetonitrile / 0.5 h / 0 °C / Inert atmosphere

6.2: -40 - 20 °C / Inert atmosphere

6.3: 20 °C / Inert atmosphere

With di-isopropyl azodicarboxylate; potassium tert-butylate; toluene-4-sulfonic acid; 9-bora-bicyclo[3.3.1]nonane; triphenylphosphine; In tetrahydrofuran; diethyl ether; water; N,N-dimethyl-formamide; acetone; acetonitrile; tert-butyl alcohol; 1.1: Sharpless dihydroxylation / 4.1: Hydroboration reaction / 5.1: Mitsunobu reaction / 5.3: Mitsunobu reaction / 6.1: Mitsunobu reaction / 6.2: Mitsunobu reaction;
DOI:10.1002/ejoc.201001473