methyl 4,6-O-benzylidene-α-D-arabino-2-hexulopyranoside O-methyloxime

Base Information

• Chemical Name: methyl 4,6-O-benzylidene-α-D-arabino-2-hexulopyranoside O-methyloxime
• CAS No.: 128583-64-2
• Molecular Formula: C₁₅H₁₉NO₆
• Molecular Weight: 309.319
• Mol file: 128583-64-2.mol

Synonyms:methyl 4,6-O-benzylidene-α-D-arabino-2-hexulopyranoside O-methyloxime

Chemical Property of methyl 4,6-O-benzylidene-α-D-arabino-2-hexulopyranoside O-methyloxime

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 4,6-O-benzylidene-α-D-arabino-2-hexulopyranoside O-methyloxime

There total 1 articles about methyl 4,6-O-benzylidene-α-D-arabino-2-hexulopyranoside O-methyloxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

N-methoxylamine hydrochloride (593-56-6) + methyl 4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose (126924-10-5) → methyl 4,6-O-benzylidene-α-D-arabino-2-hexulopyranoside O-methyloxime (128583-64-2)

Guidance literature:

With sodium hydrogencarbonate; In methanol; for 2h; Heating;

DOI:10.1248/cpb.37.2673

Reference yield:

acetic anhydride (108-24-7) + methyl 4,6-O-benzylidene-α-D-arabino-2-hexulopyranoside O-methyloxime (128583-64-2) → methyl 2-acetamido-3-O-acetyl-4,6-O-benzylidene-2-deoxy-α-D-mannopyranoside (128657-65-8) + methyl 2-acetamido-3-O-acetyl-4,6-di-O-benzylidene-2-deoxy-α-D-glucopyranoside (6748-94-3,35439-46-4,52885-38-8,78216-84-9,98574-00-6,99944-67-9,109121-60-0,109121-61-1,110658-08-7,128657-65-8,129784-18-5,139894-30-7,87303-57-9)

Guidance literature:

With pyridine; aluminium hydride; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, r.t.;

DOI:10.1248/cpb.37.2673

upstream raw materials:

N-methoxylamine hydrochloride

methyl 4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose

Downstream raw materials:

methyl 2-acetamido-3-O-acetyl-4,6-O-benzylidene-2-deoxy-α-D-mannopyranoside

methyl 2-acetamido-3-O-acetyl-4,6-di-O-benzylidene-2-deoxy-α-D-glucopyranoside