(4-bromo-3-(dimethoxymethyl)phenoxy)(tert-butyl) dimethylsilane

Base Information

• Chemical Name: (4-bromo-3-(dimethoxymethyl)phenoxy)(tert-butyl) dimethylsilane
• CAS No.: 959687-74-2
• Molecular Formula: C₁₅H₂₅BrO₃Si
• Molecular Weight: 361.351
• Mol file: 959687-74-2.mol

Synonyms:(4-bromo-3-(dimethoxymethyl)phenoxy)(tert-butyl) dimethylsilane

Chemical Property of (4-bromo-3-(dimethoxymethyl)phenoxy)(tert-butyl) dimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (4-bromo-3-(dimethoxymethyl)phenoxy)(tert-butyl) dimethylsilane

There total 2 articles about (4-bromo-3-(dimethoxymethyl)phenoxy)(tert-butyl) dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-bromo-3-(dimethoxymethyl)phenol + tert-butyldimethylsilyl chloride (18162-48-6) → (4-bromo-3-(dimethoxymethyl)phenoxy)(tert-butyl) dimethylsilane (959687-74-2)

Guidance literature:

With 1H-imidazole; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1021/jacs.7b04804

Reference yield:

→ (4-bromo-3-(dimethoxymethyl)phenoxy)(tert-butyl) dimethylsilane (959687-74-2)

Guidance literature:

Reference yield: 78.0%

(4-bromo-3-(dimethoxymethyl)phenoxy)(tert-butyl) dimethylsilane (959687-74-2) + phosphorous acid trimethyl ester (121-45-9) → C16H28BrO5PSi

Guidance literature:

(4-bromo-3-(dimethoxymethyl)phenoxy)(tert-butyl) dimethylsilane; phosphorous acid trimethyl ester; In dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere;

With titanium tetrachloride; In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/jacs.7b04804

upstream raw materials:

tert-butyldimethylsilyl chloride