[(dcpe)Ni(pdt)Fe(CO)₃]

Base Information

• Chemical Name: [(dcpe)Ni(pdt)Fe(CO)₃]
• CAS No.: 1332326-92-7
• Molecular Formula: C₃₂H₅₄FeNiO₃P₂S₂
• Molecular Weight: 727.395
• Mol file: 1332326-92-7.mol

Synonyms:[(dcpe)Ni(pdt)Fe(CO)₃]

Chemical Property of [(dcpe)Ni(pdt)Fe(CO)₃]

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(dcpe)Ni(pdt)Fe(CO)₃]

There total 2 articles about [(dcpe)Ni(pdt)Fe(CO)₃] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

diiodotetracarbonyliron(II) (15616-56-5,14911-55-8,14878-30-9) + [nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)] (1332327-06-6) → [(dcpe)Ni(pdt)Fe(CO)3] (1332326-92-7)

Guidance literature:

With (C₅H₅)2Co; In dichloromethane; using Schlenk techniques; CH2Cl2 added to mixt. of Fe complex and Ni complex at -78°C; treated with (C5H5)2Co; stirred at room temp. for 1 h; evapd. under reduced pressure; washed and sonicated with MeCN; extd. into CH2Cl2; filtered through Celite; filtrate concd. to dryness under vac.;

DOI:10.1021/ic2012759

Reference yield:

[(1,2-bis(dicyclohexylphosphino)ethane)dichloronickel(II)] (96555-88-3) → [(dcpe)Ni(pdt)Fe(CO)3] (1332326-92-7)

Guidance literature:

Multi-step reaction with 2 steps

1: NaOMe / dichloromethane; methanol

2: (C₅H₅)2Co / dichloromethane

With NaOMe; (C₅H₅)2Co; In methanol; dichloromethane;

DOI:10.1021/ic2012759

Reference yield: 78.0%

ferrocenium(III) tetrafluoroborate (1282-37-7) + dichloromethane (75-09-2) + [(dcpe)Ni(pdt)Fe(CO)3] (1332326-92-7) → [(Cy2PCH2CH2PCy2)Ni(propaneditiolate)Fe(CO)3]BF4*2.25CH2Cl2

Guidance literature:

With pentane; In dichloromethane; MBraun glovebox, under N2; soln. of NiFe compd. and FcBF4 in CH2Cl2 stirred (1 min), pentane (-28°C) added, 10 min at -28°C; filtered, washed (-28°C, pentane); elem. anal.;

DOI:10.1021/ic202329y

upstream raw materials:

diiodotetracarbonyliron(II)

[nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)]

[(1,2-bis(dicyclohexylphosphino)ethane)dichloronickel(II)]

Downstream raw materials:

[HNiFe(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)(CO)3]BF₄*CH₂Cl₂