[nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)]

Base Information

• Chemical Name: [nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)]
• CAS No.: 1332327-06-6
• Molecular Formula: C₂₉H₅₄NiP₂S₂
• Molecular Weight: 587.517
• Mol file: 1332327-06-6.mol

Synonyms:[nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)]

Chemical Property of [nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)]

There total 1 articles about [nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1.3-propanedithiol (109-80-8) + [(1,2-bis(dicyclohexylphosphino)ethane)dichloronickel(II)] (96555-88-3) → [nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)] (1332327-06-6)

Guidance literature:

With NaOMe; In methanol; dichloromethane; byproducts: NaCl; unsing Schlenk techniques; soln. of Ni complex in CH2Cl2 treated with ligand and then with soln. of NaOMe in MeOH; stirred at room temp. for 15 min; solvent removed under reduced pressure; extd. into CH2Cl2; filtered through Celite; filtrate evapd.; elem. anal.;

DOI:10.1021/ic2012759

Reference yield: 96.0%

cis-(piperidino)2Mo(CO)4 + [nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)] (1332327-06-6) → [(dcpe)Ni(pdt)Mo(CO)4]

Guidance literature:

In dichloromethane; for 0.25h; Inert atmosphere;

DOI:10.1002/ejic.201500740

Reference yield: 72.0%

dichloromethane (75-09-2) + [nickel(II)(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)] (1332327-06-6) + cis-[W(CO)4(piperidine)2] → [(dcpe)Ni(pdt)W(CO)4]*0.5(CH2Cl2)

Guidance literature:

for 1h; Inert atmosphere; Reflux;

DOI:10.1002/ejic.201500740

upstream raw materials:

1.3-propanedithiol

[(1,2-bis(dicyclohexylphosphino)ethane)dichloronickel(II)]

Downstream raw materials:

[HNiFe(1,3-propanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)(CO)3]BF₄*CH₂Cl₂

[(dcpe)Ni(pdt)Fe(CO)₃]