diphenylphosphinic acid N-methyl-(S)-α-methylbenzylamide

Base Information

Chemical Name:diphenylphosphinic acid N-methyl-(S)-α-methylbenzylamide
CAS No.:874280-81-6
Molecular Formula:C₂₁H₂₂NOP
Molecular Weight:335.386
Hs Code.:

Synonyms:diphenylphosphinic acid N-methyl-(S)-α-methylbenzylamide

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Chemical Property of diphenylphosphinic acid N-methyl-(S)-α-methylbenzylamide

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Technology Process of diphenylphosphinic acid N-methyl-(S)-α-methylbenzylamide

There total 8 articles about diphenylphosphinic acid N-methyl-(S)-α-methylbenzylamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 82637-15-8
(S)-N-(1-phenylethyl)diphenylphosphinamide

: 74-88-4
methyl iodide

: 874280-81-6
diphenylphosphinic acid N-methyl-(S)-α-methylbenzylamide

Guidance literature:: (S)-N-(1-phenylethyl)diphenylphosphinamide; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere; Schlenk technique;

methyl iodide; In tetrahydrofuran-d8; hexane; at -78 ℃; Inert atmosphere; Schlenk technique;
DOI:10.1039/c4ob02440k

Reference yield:

: 62369-76-0
P-diphenyl(N-benzyl-N-methyl)-λ⁵-phosphinamide

: 333-27-7
methyl trifluoromethanesulfonate

: 874280-81-6
diphenylphosphinic acid N-methyl-(S)-α-methylbenzylamide

: 156698-95-2
N-methyl-P,P-diphenyl-N-[(1R)-1-phenylethyl]phosphinic amide

Guidance literature:: P-diphenyl(N-benzyl-N-methyl)-λ⁵-phosphinamide; With n-butyllithium; (-)-sparteine; In hexane; toluene; at -90 ℃; for 0.333333h; Inert atmosphere;

methyl trifluoromethanesulfonate; In hexane; toluene; at -90 ℃; for 0.0833333h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol801027p

Reference yield:

: 62369-76-0
P-diphenyl(N-benzyl-N-methyl)-λ⁵-phosphinamide

: 74-88-4
methyl iodide

: 874280-81-6
diphenylphosphinic acid N-methyl-(S)-α-methylbenzylamide

: 156698-95-2
N-methyl-P,P-diphenyl-N-[(1R)-1-phenylethyl]phosphinic amide

Guidance literature:: P-diphenyl(N-benzyl-N-methyl)-λ⁵-phosphinamide; With n-butyllithium; (-)-sparteine; In hexane; toluene; at -90 ℃; for 1h; Inert atmosphere;

methyl iodide; In hexane; toluene; at -90 ℃; for 0.0833333h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol801027p