(S)-4-Benzyl-3-[(S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-hexanoyl]-oxazolidin-2-one

Base Information

Chemical Name:(S)-4-Benzyl-3-[(S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-hexanoyl]-oxazolidin-2-one
CAS No.:253143-32-7
Molecular Formula:C₃₃H₄₁NO₄Si
Molecular Weight:543.778
Hs Code.:

Synonyms:(S)-4-Benzyl-3-[(S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-hexanoyl]-oxazolidin-2-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-4-Benzyl-3-[(S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-hexanoyl]-oxazolidin-2-one

Chemical Property:

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Technology Process of (S)-4-Benzyl-3-[(S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-hexanoyl]-oxazolidin-2-one

There total 8 articles about (S)-4-Benzyl-3-[(S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-hexanoyl]-oxazolidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 90719-32-7
(S)-4-Benzyl-2-oxazolidinone

: C₂₈H₄₀O₄Si

: 253143-32-7
(S)-4-Benzyl-3-[(S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-hexanoyl]-oxazolidin-2-one

Guidance literature:: With lithium chloride; In tetrahydrofuran; at 20 ℃;
DOI:10.1021/ja020091v

Reference yield:

: 253143-30-5
(R)-4-benzyl-3-((S)-2-ethylpent-4-enoyl)oxazolidin-2-one

: 253143-32-7
(S)-4-Benzyl-3-[(S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-hexanoyl]-oxazolidin-2-one

Guidance literature:: Multi-step reaction with 7 steps

1.1: lithium borohydride / diethyl ether; H₂O / 0.5 h / 0 °C

2.1: 20.6 g / imidazole; 4 Angstroem molecular sieves / petroleum ether; diethyl ether; dimethylformamide / 20 °C

3.1: 9-BBN / tetrahydrofuran / 4 h / 20 °C

3.2: 92 percent / sodium hydroxide; hydroden peroxide / tetrahydrofuran; H₂O / 0 - 20 °C

4.1: pyridinium dichromate / CH₂Cl₂ / 0.5 h

5.1: 6.9 g / sodium chlorite; sulfamic acid / tetrahydrofuran; H₂O / 0 - 20 °C

6.1: triethylamine / tetrahydrofuran / -78 - 0 °C

7.1: 5.53 g / lithium chloride / tetrahydrofuran / 20 °C

With 1H-imidazole; sodium chlorite; dipyridinium dichromate; lithium borohydride; 9-borabicyclo[3.3.1]nonane dimer; 4 A molecular sieve; aminosulfonic acid; triethylamine; lithium chloride; In tetrahydrofuran; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; Petroleum ether;
DOI:10.1021/ja020091v

Reference yield:

: 253143-31-6
4-(tert-butyl-diphenyl-silanyloxymethyl)-hexan-1-ol

: 253143-32-7
(S)-4-Benzyl-3-[(S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-hexanoyl]-oxazolidin-2-one

Guidance literature:: Multi-step reaction with 4 steps

1: pyridinium dichromate / CH₂Cl₂ / 0.5 h

2: 6.9 g / sodium chlorite; sulfamic acid / tetrahydrofuran; H₂O / 0 - 20 °C

3: triethylamine / tetrahydrofuran / -78 - 0 °C

4: 5.53 g / lithium chloride / tetrahydrofuran / 20 °C

With sodium chlorite; dipyridinium dichromate; aminosulfonic acid; triethylamine; lithium chloride; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/ja020091v