carbonyl{bis(triphenylphosphine)}rhodium(I) fluoride

Base Information

• Chemical Name: carbonyl{bis(triphenylphosphine)}rhodium(I) fluoride
• CAS No.: 22481-17-0
• Molecular Formula: C₃₇H₃₀FOP₂Rh
• Molecular Weight: 674.496
• Mol file: 22481-17-0.mol

Synonyms:carbonyl{bis(triphenylphosphine)}rhodium(I) fluoride

Chemical Property of carbonyl{bis(triphenylphosphine)}rhodium(I) fluoride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of carbonyl{bis(triphenylphosphine)}rhodium(I) fluoride

There total 8 articles about carbonyl{bis(triphenylphosphine)}rhodium(I) fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) + tris(dimethylamino)sulfonium trimethylsilyldifluoride (150746-76-2) → carbonyl{bis(triphenylphosphine)}rhodium(I) fluoride (22481-17-0)

Guidance literature:

In tetrahydrofuran; byproducts: [(CH3)2N)3S]Cl; anhydrous and anaerobic conditions; stirring (30 min, 25°C); filtn., solvent removal, recrystallization (CHCl3);

DOI:10.1016/0277-5387(94)00355-I

Reference yield:

FRh(C2F4)(P(C6H5)3)2 (107272-42-4) → fluorocarbonylbis(triphenylphosphine)rhodium(I) (58167-05-8,22481-17-0)

Guidance literature:

With CO; In dichloromethane; Soln. of complex in CH2Cl2 was treated with CO;; ether-pentane was added, cooled to -35°C for 24 h;;

DOI:10.1021/om00148a016

Reference yield:

fluorotris(triphenylphosphine)rhodium(I) + carbon monoxide (201230-82-2) → carbonyl{bis(triphenylphosphine)}rhodium(I) fluoride (22481-17-0)

Guidance literature:

In N,N-dimethyl-formamide; at 90°C; NMR, IR;

DOI:10.1021/ja049844z

upstream raw materials:

carbon monoxide

trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I)

tris(dimethylamino)sulfonium trimethylsilyldifluoride

fluorotris(triphenylphosphine)rhodium(I)

Downstream raw materials:

carbonyl(η1-O-1-phenyl-1-oxyethenyl){bis(triphenylphosphine)}rhodium(I)

[Rh(SC₃H₆P(C₆H₅)2)(CO)(P(C₆H₅)3)]

[Rh(S(C₆H₄)P(C₆H₅)2)(CO)(P(C₆H₅)3)]

[Rh2(μ-TIPBT)2(CO)2(PPh3)2]