[(R)-3-(2-Allyloxy-3-methoxy-phenyl)-3-formyl-6-oxo-heptyl]-methyl-carbamic acid benzyl ester

Base Information

Chemical Name:[(R)-3-(2-Allyloxy-3-methoxy-phenyl)-3-formyl-6-oxo-heptyl]-methyl-carbamic acid benzyl ester
CAS No.:80754-81-0
Molecular Formula:C₂₇H₃₃NO₆
Molecular Weight:467.562
Hs Code.:

Synonyms:[(R)-3-(2-Allyloxy-3-methoxy-phenyl)-3-formyl-6-oxo-heptyl]-methyl-carbamic acid benzyl ester

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Chemical Property of [(R)-3-(2-Allyloxy-3-methoxy-phenyl)-3-formyl-6-oxo-heptyl]-methyl-carbamic acid benzyl ester

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Technology Process of [(R)-3-(2-Allyloxy-3-methoxy-phenyl)-3-formyl-6-oxo-heptyl]-methyl-carbamic acid benzyl ester

There total 13 articles about [(R)-3-(2-Allyloxy-3-methoxy-phenyl)-3-formyl-6-oxo-heptyl]-methyl-carbamic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 78166-97-9
2-hydroxy-3-methoxybenzaldehyde sodium salt

: 80754-81-0
[(R)-3-(2-Allyloxy-3-methoxy-phenyl)-3-formyl-6-oxo-heptyl]-methyl-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / dimethylformamide / 12 h / 25 °C

2: 1.) THF, 25 deg C, 5 min, 2.) Jones oxidation (0 deg C, 30 min)

3: 90 percent / Camphorsulfonic Acid / 25 °C

4: n-Butyllithium

With n-butyllithium; camphor-10-sulfonic acid; In N,N-dimethyl-formamide;
DOI:10.1021/jo00330a045

Reference yield:

: 23343-06-8
2-allyloxy-3-methoxy-benzaldehyde

: 80754-81-0
[(R)-3-(2-Allyloxy-3-methoxy-phenyl)-3-formyl-6-oxo-heptyl]-methyl-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

2: pyridinium dichromate / dimethylformamide / 1.) 0 deg C, 0.5 h, 2.) RT, 4 h

4: 1N HCl / 6 h / Ambient temperature

With hydrogenchloride; dipyridinium dichromate; In N,N-dimethyl-formamide;
DOI:10.1021/jo00347a029

Reference yield:

: 78166-98-0
1-<2-(allyloxy)-3-methoxyphenyl>-2-propenone

: 80754-81-0
[(R)-3-(2-Allyloxy-3-methoxy-phenyl)-3-formyl-6-oxo-heptyl]-methyl-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / camphorsulfonic acid / 36 h / Ambient temperature

2: n-butyllithium / tetrahydrofuran / 2 h / Heating

3: 2.) HMPA / 1.) THF, -78 deg C, 1 h, 2.) THF, RT

4: 1N HCl / 6 h / Ambient temperature

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; camphor-10-sulfonic acid; In tetrahydrofuran;
DOI:10.1021/jo00347a029