(CO)5ReMn(CO)4(P(C₆H₅)3)

Base Information

Chemical Name:(CO)5ReMn(CO)4(P(C₆H₅)3)
CAS No.:51320-29-7
Molecular Formula:C₂₇H₁₅MnO₉PRe
Molecular Weight:755.529
Hs Code.:

(CO)5ReMn(CO)4(P(C<sub>6</sub>H<sub>5</sub>)3)

Synonyms:(CO)5ReMn(CO)4(P(C₆H₅)3)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (CO)5ReMn(CO)4(P(C₆H₅)3)

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Technology Process of (CO)5ReMn(CO)4(P(C₆H₅)3)

There total 16 articles about (CO)5ReMn(CO)4(P(C₆H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 16457-30-0
hydridopentacarbonylrhenium(I)

: pentacarbonyl(methyl)manganese(I)

: 51320-29-7
(CO)5ReMn(CO)4(P(C₆H₅)3)

: 75-07-0,9002-91-9
acetaldehyde

Guidance literature:: With triphenylphosphine; THF; In tetrahydrofuran; MeMn(CO)5, HRe(CO)5 (1:1 molar ratio), and THF were distilled into a reaction bulb, mixt. was stirred for 1 d at room temp., PPh3 in CH2Cl2 wasadded, soln. was stirred for 2 d in the dark at room temp.; organometallic product was isolated via preparative layer chromy.; yield of MeCHO was detd. in a expt. in THF-d8 by integration of the corresponding peak in (1)H NMR spectrum;

Reference yield: 40.0%

: 13859-41-1
sodium-manganese pentacarbonyl

: 70083-75-9
pentacarbonyl(triphenylphosphane)rhenium tetrafluoroborate

: 51320-28-6,51320-29-7
(OC)5MnRe(CO)4P(C₆H₅)3

Guidance literature:: In tetrahydrofuran; byproducts: (OC)5Re-Re(CO)5, NaBF4, CO; under N2, suspn. of Re-complex in THF, addn. of soln. NaMn(CO)5 in THF under stirring at -78 ° C, stirring at room temp. for 20 min; sepn. of NaBF4, evapn. of THF, residue stirred for 10 min at -78 °C in methanol, sepn. of residue from soln., dried in high vac., sublimation at 50 °C; elem. anal.;
DOI:10.1016/0022-328X(89)87258-4

Reference yield:

: 14693-30-2
decacarbonylmanganeserhenium

Mn(CO)4(P(C₆H₅)3)Re(CO)5: 51320-29-7,51320-28-6
Mn(CO)4(P(C₆H₅)3)Re(CO)5

: 51320-28-6,51320-29-7
Mn(CO)5Re(CO)4(P(C₆H₅)3)

Guidance literature:: With carbon monoxide; triphenylphosphine; In decane; byproducts: CO; under CO (2 atm); 110.5-130°C; IR; Kinetics;
DOI:10.1021/ja00530a029