(3S,5R)-3-Methyl-3-(4-methyl-pent-3-enyl)-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene

Base Information

Chemical Name:(3S,5R)-3-Methyl-3-(4-methyl-pent-3-enyl)-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene
CAS No.:139177-30-3
Molecular Formula:C₁₉H₃₈OSi₂
Molecular Weight:338.681
Hs Code.:

Synonyms:(3S,5R)-3-Methyl-3-(4-methyl-pent-3-enyl)-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene

Suppliers and Price of (3S,5R)-3-Methyl-3-(4-methyl-pent-3-enyl)-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3S,5R)-3-Methyl-3-(4-methyl-pent-3-enyl)-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3S,5R)-3-Methyl-3-(4-methyl-pent-3-enyl)-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene

There total 1 articles about (3S,5R)-3-Methyl-3-(4-methyl-pent-3-enyl)-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 917-64-6
methyl magnesium iodide

: 75-77-4
chloro-trimethyl-silane

: 139177-29-0
(R)-3-(4-Methyl-pent-3-enyl)-5-trimethylsilanyl-cyclohex-2-enone

: 139177-30-3
(3S,5R)-3-Methyl-3-(4-methyl-pent-3-enyl)-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(I) bromide dimethylsulfide complex; In tetrahydrofuran; at -78 ℃; for 0.5h;
DOI:10.1016/0040-4039(91)80536-F

Reference yield:

: 139177-30-3
(3S,5R)-3-Methyl-3-(4-methyl-pent-3-enyl)-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene

: 70447-87-9
(+)-Magydardienediol

Guidance literature:: Multi-step reaction with 7 steps

1: 1) MeLi / 1) 0 deg C, 1 h, 2) THF, 0 deg C, 2 h

3: 95 percent / L-selectride / tetrahydrofuran / -78 °C

4: LDA / tetrahydrofuran / -78 °C

5: TiCl₄, Zn / 4 h / Ambient temperature

6: 79 percent / t-BuOOH / VO(acac)2 / toluene / 1.5 h / Ambient temperature

7: 74 percent / LiAlH₄ / 1 h / Ambient temperature

With tert.-butylhydroperoxide; lithium aluminium tetrahydride; methyllithium; titanium tetrachloride; L-Selectride; zinc; lithium diisopropyl amide; bis(acetylacetonate)oxovanadium; In tetrahydrofuran; toluene;
DOI:10.1016/0040-4039(91)80536-F

Reference yield:

: 139177-30-3
(3S,5R)-3-Methyl-3-(4-methyl-pent-3-enyl)-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene

: 139241-11-5
(2R,3R)-3-Methyl-2-(3-methyl-but-2-enyl)-3-(4-methyl-pent-3-enyl)-cyclohexanone

Guidance literature:: Multi-step reaction with 3 steps

1: 1) MeLi / 1) 0 deg C, 1 h, 2) THF, 0 deg C, 2 h

3: 95 percent / L-selectride / tetrahydrofuran / -78 °C

With methyllithium; L-Selectride; In tetrahydrofuran;
DOI:10.1016/0040-4039(91)80536-F