C₁₁H₁₄LiNOSi

Base Information

• Chemical Name: C₁₁H₁₄LiNOSi
• CAS No.: 56346-03-3
• Molecular Formula: C₁₁H₁₄LiNOSi
• Molecular Weight: 211.265
• Mol file: 56346-03-3.mol

Synonyms:C₁₁H₁₄LiNOSi

Chemical Property of C₁₁H₁₄LiNOSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₁H₁₄LiNOSi

There total 1 articles about C₁₁H₁₄LiNOSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenyl(trimethylsiloxy)acetonitrile (25438-37-3) → C11H14LiNOSi (56346-03-3)

Guidance literature:

With lithium diisopropyl amide; In diethyl ether; at -78 ℃; Title compound not separated from byproducts;

Reference yield:

ethene (74-85-1) + C11H14LiNOSi (56346-03-3) → 1-phenyl-propan-1-one (93-55-0)

Guidance literature:

Yield given. Multistep reaction;

DOI:10.1021/ja00535a026

Reference yield:

C11H14LiNOSi (56346-03-3) → 7-exo-benzoylbicyclo<4.1.0>heptane (31152-14-4)

Guidance literature:

Multi-step reaction with 3 steps

2: pyridine

3: N-methylimidazole / CH₂Cl₂ / Irradiation

With 1-methyl-1H-imidazole; In pyridine; dichloromethane;

DOI:10.1002/1521-3773(20010316)40:6<1064::AID-ANIE10640>3.0.CO;2-5

upstream raw materials:

phenyl(trimethylsiloxy)acetonitrile

Downstream raw materials:

3-benzoylpropionic acid methyl ester

5,5-dimethyl-3-benzoyl-2-cyclohexen-1-one

α-<5,5-Dimethyl-3-(trimethylsiloxy)-2-cyclohexen-1-yl>-α-(trimethylsiloxy)benzolacetonitril

α-(Trimethylsiloxy)-α-<3-(trimethylsiloxy)-2-cyclohexen-1-yl>benzolacetonitril