1′-(dicyclohexylphosphino)-1-hydroxymethylferrocene-borane(1/1)

Base Information

• Chemical Name: 1′-(dicyclohexylphosphino)-1-hydroxymethylferrocene-borane(1/1)
• CAS No.: 1423762-47-3
• Molecular Formula: C₂₃H₃₆BFeOP
• Molecular Weight: 426.17
• Mol file: 1423762-47-3.mol

Synonyms:1′-(dicyclohexylphosphino)-1-hydroxymethylferrocene-borane(1/1)

Chemical Property of 1′-(dicyclohexylphosphino)-1-hydroxymethylferrocene-borane(1/1)

Chemical Property:

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Technology Process of 1′-(dicyclohexylphosphino)-1-hydroxymethylferrocene-borane(1/1)

There total 1 articles about 1′-(dicyclohexylphosphino)-1-hydroxymethylferrocene-borane(1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1'-(dicyclohexylphosphino)ferrocene-1-carbaldehyde (1423762-40-6) + borane tetrahydrofuran → 1′-(dicyclohexylphosphino)-1-hydroxymethylferrocene-borane(1/1) (1423762-47-3)

Guidance literature:

With sodium tetrahydroborate; In tetrahydrofuran; at 0 ℃; for 1.5h;

DOI:10.1039/c2dt32511j

Reference yield: 27.0%

dimethylsulfide borane complex (13292-87-0) + 1′-(dicyclohexylphosphino)-1-hydroxymethylferrocene-borane(1/1) (1423762-47-3) + diphenylphosphane (829-85-6) → 1'-(dicyclohexylphosphino)-1-[(diphenylphosphino)methyl]ferrocene-borane + C23H36BFeP

Guidance literature:

1′-(dicyclohexylphosphino)-1-hydroxymethylferrocene-borane(1/1); diphenylphosphane; With chloro-trimethyl-silane; sodium iodide; In acetonitrile; at 20 ℃; for 18h; Inert atmosphere; Schlenk technique;

dimethylsulfide borane complex; In acetonitrile; for 0.0833333h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2018.01.009

upstream raw materials:

1'-(dicyclohexylphosphino)ferrocene-1-carbaldehyde