(+)-methyl (2E,6R)-6-({[(phenylmethyl)oxy]carbonyl}amino)-7-[(triphenylmethyl)oxy]hept-2-enoate

Base Information

Chemical Name:(+)-methyl (2E,6R)-6-({[(phenylmethyl)oxy]carbonyl}amino)-7-[(triphenylmethyl)oxy]hept-2-enoate
CAS No.:1315128-36-9
Molecular Formula:C₃₅H₃₅NO₅
Molecular Weight:549.667
Hs Code.:

Synonyms:(+)-methyl (2E,6R)-6-({[(phenylmethyl)oxy]carbonyl}amino)-7-[(triphenylmethyl)oxy]hept-2-enoate

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Chemical Property of (+)-methyl (2E,6R)-6-({[(phenylmethyl)oxy]carbonyl}amino)-7-[(triphenylmethyl)oxy]hept-2-enoate

Chemical Property:

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Technology Process of (+)-methyl (2E,6R)-6-({[(phenylmethyl)oxy]carbonyl}amino)-7-[(triphenylmethyl)oxy]hept-2-enoate

There total 5 articles about (+)-methyl (2E,6R)-6-({[(phenylmethyl)oxy]carbonyl}amino)-7-[(triphenylmethyl)oxy]hept-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6213-88-3
(E)-methyl 3-iodoacrylate

: C₃₉H₄₄BNO₃

: 1315128-36-9
(+)-methyl (2E,6R)-6-({[(phenylmethyl)oxy]carbonyl}amino)-7-[(triphenylmethyl)oxy]hept-2-enoate

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate; N,N-dimethyl-formamide; In tetrahydrofuran; water; at 20 ℃; Inert atmosphere;
DOI:10.1002/chem.201100649

Reference yield:

: cinnamyl methyl carbonate

: 1315128-36-9
(+)-methyl (2E,6R)-6-({[(phenylmethyl)oxy]carbonyl}amino)-7-[(triphenylmethyl)oxy]hept-2-enoate

Guidance literature:: Multi-step reaction with 4 steps

1: bis(1,5-cyclooctadiene)diiridium(I) dichloride; C₃₇H₃₂NO₃P; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

2: potassium hydroxide / methanol / 1 h / 20 °C

3: tetrahydrofuran / 3 h / 50 °C / Inert atmosphere

4: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate; N,N-dimethyl-formamide / tetrahydrofuran; water / 20 °C / Inert atmosphere

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; bis(1,5-cyclooctadiene)diiridium(I) dichloride; triphenyl-arsane; C₃₇H₃₂NO₃P; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine; caesium carbonate; N,N-dimethyl-formamide; potassium hydroxide; In tetrahydrofuran; methanol; water; 4: Suzuki-Miyaura coupling;
DOI:10.1002/chem.201100649

Reference yield:

: 1315128-16-5
phenylmethyl formyl((1R)-1-{[(triphenylmethyl)oxy]methyl}prop-2-en-1-yl)carbamate

: 1315128-36-9
(+)-methyl (2E,6R)-6-({[(phenylmethyl)oxy]carbonyl}amino)-7-[(triphenylmethyl)oxy]hept-2-enoate

Guidance literature:: Multi-step reaction with 3 steps

1: potassium hydroxide / methanol / 1 h / 20 °C

2: tetrahydrofuran / 3 h / 50 °C / Inert atmosphere

3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate; N,N-dimethyl-formamide / tetrahydrofuran; water / 20 °C / Inert atmosphere

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate; N,N-dimethyl-formamide; potassium hydroxide; In tetrahydrofuran; methanol; water; 3: Suzuki-Miyaura coupling;
DOI:10.1002/chem.201100649