2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)

Base Information

Chemical Name:2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)
CAS No.:942608-43-7
Molecular Formula:C₄₄H₄₂P₂Ru
Molecular Weight:733.835
Hs Code.:

Synonyms:2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)

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Chemical Property of 2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)

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Technology Process of 2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)

There total 1 articles about 2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 942608-42-6
2-(2'-P(O)Ph2-naphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)

: 4559-70-0
Diphenylphosphine oxide

: 942608-43-7
2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)

Guidance literature:: With poly(methylhydrosiloxane); titanium tetra(isopropoxide); sodium hydrogen carbonate; In tetrahydrofuran; (N2 or Ar); using Schlenk techniques; mixing of (Me5C5)Ru(C4PMe2PhC10H6POPh2), poly(methylhydrosiloxane) (100 equiv.) and titanium tetra(isopropoxide) (1.5 equiv.) in THF; reflux for 4 h; monitoring by NMR; cooling in ice bath; addn. dropwise aq. NaOH; sepn. of org. layer; extn. of aq. layer with CH2Cl2; combining of CH2Cl2 layers; drying over MgSO4; filtration, removal of CH2Cl2 under reduced pressure;
DOI:10.1021/om0610905

Reference yield: 64.0%

: 12080-32-9
dichloro( 1,5-cyclooctadiene)platinum(ll)

: 75-09-2
dichloromethane

: 942608-43-7
2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)

: cis-[2-(2'-diphenylphosphanyl-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)Ru]PtCl2*2CH2Cl2

Guidance literature:: In chloroform; (N2 or Ar); using Schlenk techniques; dissolving of (Me5C5)Ru(C4PMe2PhC10H6PPh2) in CHCl3; addn. to stirred chloroform soln. of PtCl2(COD) at -60°C; stirring for 15 min; warming to room temp., evapn. to dryness under reduced pressure, crystn.by slow diffusion of MeOH into soln. in CH2Cl2; elem. anal.;
DOI:10.1021/om0610905