methyl 3-(2,7-diphenylheptylamino)-5-nitrobenzoate

Base Information

Chemical Name:methyl 3-(2,7-diphenylheptylamino)-5-nitrobenzoate
CAS No.:1610566-96-5
Molecular Formula:C₂₇H₃₀N₂O₄
Molecular Weight:446.546
Hs Code.:

Synonyms:methyl 3-(2,7-diphenylheptylamino)-5-nitrobenzoate

Suppliers and Price of methyl 3-(2,7-diphenylheptylamino)-5-nitrobenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 3-(2,7-diphenylheptylamino)-5-nitrobenzoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 3-(2,7-diphenylheptylamino)-5-nitrobenzoate

There total 6 articles about methyl 3-(2,7-diphenylheptylamino)-5-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 6307-87-5
methyl 3-bromo-5-nitrobenzoate

: 1172847-66-3
2,7-diphenylheptan-1-amine

: 1610566-96-5
methyl 3-(2,7-diphenylheptylamino)-5-nitrobenzoate

Guidance literature:: With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In toluene; at 100 ℃; for 12h; Schlenk technique; Inert atmosphere;
DOI:10.1002/cmdc.201400044

Reference yield:

: 6307-83-1
3-bromo-5-nitro-benzoic acid

: 1610566-96-5
methyl 3-(2,7-diphenylheptylamino)-5-nitrobenzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: oxalyl dichloride / tetrahydrofuran; N,N-dimethyl-formamide / 1 h / 20 °C

1.2: 0 °C

2.1: caesium carbonate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / 12 h / 100 °C / Schlenk technique; Inert atmosphere

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; oxalyl dichloride; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In tetrahydrofuran; N,N-dimethyl-formamide; toluene;
DOI:10.1002/cmdc.201400044

Reference yield:

: 14469-83-1
(5-bromopentyl)benzene

: 1610566-96-5
methyl 3-(2,7-diphenylheptylamino)-5-nitrobenzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium amide / toluene / 17 h / 80 °C

2.1: hydrogenchloride; palladium on activated charcoal; hydrogen / methanol; water / 20 h / 25 °C

2.2: 0 °C

3.1: caesium carbonate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / 12 h / 100 °C / Schlenk technique; Inert atmosphere

With hydrogenchloride; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; palladium on activated charcoal; hydrogen; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium amide; In methanol; water; toluene;
DOI:10.1002/cmdc.201400044