(2R,4R)-4-Benzyloxy-2-methyl-4-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-1-ol

Base Information

Chemical Name:(2R,4R)-4-Benzyloxy-2-methyl-4-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-1-ol
CAS No.:114114-22-6
Molecular Formula:C₂₄H₃₈O₄
Molecular Weight:390.563
Hs Code.:

Synonyms:(2R,4R)-4-Benzyloxy-2-methyl-4-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-1-ol

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Chemical Property of (2R,4R)-4-Benzyloxy-2-methyl-4-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-1-ol

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Technology Process of (2R,4R)-4-Benzyloxy-2-methyl-4-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-1-ol

There total 14 articles about (2R,4R)-4-Benzyloxy-2-methyl-4-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 114114-21-5
{(2R,4R)-4-Benzyloxy-4-[(4R,5S,6R)-2-(4-methoxy-phenyl)-5-methyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-2-methyl-pentyloxy}-tert-butyl-dimethyl-silane

: 67-64-1
acetone

: 114114-22-6
(2R,4R)-4-Benzyloxy-2-methyl-4-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-1-ol

Guidance literature:: With phthalic acid dimethyl ester; toluene-4-sulfonic acid; at 25 ℃; for 12h;
DOI:10.1016/S0040-4020(01)96139-3

Reference yield: 95.0%

: 114114-21-5
{(2R,4R)-4-Benzyloxy-4-[(4R,5S,6R)-2-(4-methoxy-phenyl)-5-methyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-2-methyl-pentyloxy}-tert-butyl-dimethyl-silane

: 114114-22-6
(2R,4R)-4-Benzyloxy-2-methyl-4-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-1-ol

Guidance literature:: With toluene-4-sulfonic acid; In acetone; for 12h;
DOI:10.1007/BF00958058

Reference yield:

: 114137-89-2
(3S,4R,5S,6R,7R,9R)-7-Benzyloxy-10-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-3,5,7,9-tetramethyl-dec-1-en-4-ol

: 114114-22-6
(2R,4R)-4-Benzyloxy-2-methyl-4-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / DDQ, 3 Angstroem molecular sieves / CH₂Cl₂ / 0.5 h / 25 °C

2: 95 percent / TsOH*H₂O, DMP / 12 h / 25 °C

With phthalic acid dimethyl ester; 3 A molecular sieve; toluene-4-sulfonic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane;
DOI:10.1016/S0040-4020(01)96139-3