(1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl 3'-chlorobenzoate

Base Information

Chemical Name:(1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl 3'-chlorobenzoate
CAS No.:170873-07-1
Molecular Formula:C₁₉H₁₄Cl₂O₄Se
Molecular Weight:456.184
Hs Code.:

Synonyms:(1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl 3'-chlorobenzoate

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Chemical Property of (1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl 3'-chlorobenzoate

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Technology Process of (1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl 3'-chlorobenzoate

There total 3 articles about (1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl 3'-chlorobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 128573-16-0
(-)-(1S,4R,5R,6R)-6-endo-chloro-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-one

: (1RS,4RS)-6-Chloro-5-(phenylseleno)-7-oxabicyclo<2.2.1>hept-5-en-2-one

: 170873-06-0
(1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl acetate

: 170873-07-1
(1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl 3'-chlorobenzoate

Guidance literature:: With sodium acetate; acetic anhydride; 3-chloro-benzenecarboperoxoic acid; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, -65 deg C, 20 min, 2.) -65 deg C to 20 deg C, 40 min; 60 deg C, 1 h;
DOI:10.1021/jo00123a021

Reference yield:

: 108-24-7
acetic anhydride

: 128573-16-0
(-)-(1S,4R,5R,6R)-6-endo-chloro-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-one

: (1RS,4RS)-6-Chloro-5-(phenylseleno)-7-oxabicyclo<2.2.1>hept-5-en-2-one

: 170873-06-0
(1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl acetate

: 170873-07-1
(1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl 3'-chlorobenzoate

Guidance literature:: With sodium acetate; 3-chloro-benzenecarboperoxoic acid; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, -65 deg C, 20 min, 2.) -65 deg C to 20 deg C, 40 min; 60 deg C, 1 h;
DOI:10.1021/jo00123a021

Reference yield:

: 128573-16-0
(-)-(1S,4R,5R,6R)-6-endo-chloro-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-one

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: (1RS,4RS)-6-Chloro-5-(phenylseleno)-7-oxabicyclo<2.2.1>hept-5-en-2-one

: 170873-06-0
(1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl acetate

: 170873-07-1
(1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl 3'-chlorobenzoate

Guidance literature:: With sodium acetate; acetic anhydride; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, -65 deg C, 20 min, 2.) -65 deg C to 20 deg C, 40 min; 60 deg C, 1 h;
DOI:10.1021/jo00123a021