Ru(NCC(CN)2)(PPh₃)2Cp

Base Information

Chemical Name:Ru(NCC(CN)2)(PPh₃)2Cp
CAS No.:80659-24-1
Molecular Formula:C₄₅H₃₅N₃P₂Ru
Molecular Weight:780.811
Hs Code.:

Synonyms:Ru(NCC(CN)2)(PPh₃)2Cp

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Chemical Property of Ru(NCC(CN)2)(PPh₃)2Cp

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Technology Process of Ru(NCC(CN)2)(PPh₃)2Cp

There total 1 articles about Ru(NCC(CN)2)(PPh₃)2Cp which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 32993-05-8
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

: 34171-69-2
potassium tricyanomethanide

: 80659-24-1
Ru(NCC(CN)2)(PPh₃)2Cp

Guidance literature:: In tetrahydrofuran; methanol; (N2); refluxed for 1 h; evapd. (vac.), extd. (CH2Cl2), filtered dropwise into rapidly stirred hexane;
DOI:10.1016/j.jorganchem.2004.07.030

Reference yield: 91.0%

: ammonium hexafluorophosphate

: 32993-05-8
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

: 80659-24-1
Ru(NCC(CN)2)(PPh₃)2Cp

: [(Ru(PPh₃)2Cp)2((NC)2CCN)][PF₆]

Guidance literature:: In tetrahydrofuran; methanol; (N2); refluxed for 3 h; evapd. (vac.), extd. (CH2Cl2), added dropwise to rapidly stirred hexane;elem. anal.;
DOI:10.1016/j.jorganchem.2004.07.030

Reference yield: 81.0%

: 32993-05-8
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

: 16925-25-0
sodium hexafluoroantimonate

: 80659-24-1
Ru(NCC(CN)2)(PPh₃)2Cp

: 75-09-2
dichloromethane

: (((C₅H₅)((C₆H₅)3P)2Ru)2C(CN)3)⁽¹⁺⁾*SbF₆^(1-)*0.5CH₂Cl₂=[(((C₅H₅)((C₆H₅)3P)2Ru)2C(CN)3)]SbF₆*0.5CH₂Cl₂

Guidance literature:: In methanol; dichloromethane; under Ar; soln. of NaSbF6 in MeOH added to soln. of Cp(PPh3)2RuC(CN)3 and Cp(PPh3)2RuCl in CH2Cl2, stirred at room temp. for 4 h; evapd. in vacuo, residue dissolved in CH2Cl2, filtered, filtrate layeredwith petroleum ether, ppt. washed with Et2O, recrystd. from CH2Cl2-petr oleum ether; elem. anal.;
DOI:10.1021/ic025879t