1-[1-((1R)-1-{[(4-methoxyphenyl)methoxy]methyl}propyl)vinyloxy]-1,1-dimethyl-1-silaethane

Base Information

Chemical Name:1-[1-((1R)-1-{[(4-methoxyphenyl)methoxy]methyl}propyl)vinyloxy]-1,1-dimethyl-1-silaethane
CAS No.:332842-66-7
Molecular Formula:C₁₇H₂₈O₃Si
Molecular Weight:308.493
Hs Code.:

Synonyms:1-[1-((1R)-1-{[(4-methoxyphenyl)methoxy]methyl}propyl)vinyloxy]-1,1-dimethyl-1-silaethane

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Chemical Property of 1-[1-((1R)-1-{[(4-methoxyphenyl)methoxy]methyl}propyl)vinyloxy]-1,1-dimethyl-1-silaethane

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Technology Process of 1-[1-((1R)-1-{[(4-methoxyphenyl)methoxy]methyl}propyl)vinyloxy]-1,1-dimethyl-1-silaethane

There total 5 articles about 1-[1-((1R)-1-{[(4-methoxyphenyl)methoxy]methyl}propyl)vinyloxy]-1,1-dimethyl-1-silaethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 121-44-8
triethylamine

: 332842-79-2
(3R)-3-{[(4-methoxyphenyl)methoxy]methyl}pentan-2-one

: 332842-66-7
1-[1-((1R)-1-{[(4-methoxyphenyl)methoxy]methyl}propyl)vinyloxy]-1,1-dimethyl-1-silaethane

Guidance literature:: (3R)-3-{[(4-methoxyphenyl)methoxy]methyl}pentan-2-one; With lithium hexamethyldisilazane; In tetrahydrofuran; hexane; at -78 ℃; for 0.25h;

chloro-trimethyl-silane; triethylamine; In tetrahydrofuran; hexane; at -78 ℃; for 15h; Further stages.;
DOI:10.1021/ol015531m

Reference yield:

: 2746-25-0
p-Methoxybenzyl bromide

: 332842-66-7
1-[1-((1R)-1-{[(4-methoxyphenyl)methoxy]methyl}propyl)vinyloxy]-1,1-dimethyl-1-silaethane

Guidance literature:: Multi-step reaction with 3 steps

1.1: KH / various solvents / 5 h / -15 - 20 °C

2.1: 0.85 g / OsO₄; NaIO₄; NMO / tetrahydrofuran; H₂O; 2-methyl-propan-2-ol / 5 h / 20 °C

3.1: LiHMDS / tetrahydrofuran; hexane / 0.25 h / -78 °C

3.2: tetrahydrofuran; hexane / 15 h / -78 °C

With sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; potassium hydride; lithium hexamethyldisilazane; In tetrahydrofuran; hexane; various solvents; water; tert-butyl alcohol;
DOI:10.1021/ol015531m

Reference yield:

: 294176-65-1
(S)-2-ethyl-3-methyl-3-buten-1-ol

: 332842-66-7
1-[1-((1R)-1-{[(4-methoxyphenyl)methoxy]methyl}propyl)vinyloxy]-1,1-dimethyl-1-silaethane

Guidance literature:: Multi-step reaction with 3 steps

1.1: KH / various solvents / 5 h / -15 - 20 °C

2.1: 0.85 g / OsO₄; NaIO₄; NMO / tetrahydrofuran; H₂O; 2-methyl-propan-2-ol / 5 h / 20 °C

3.1: LiHMDS / tetrahydrofuran; hexane / 0.25 h / -78 °C

3.2: tetrahydrofuran; hexane / 15 h / -78 °C

With sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; potassium hydride; lithium hexamethyldisilazane; In tetrahydrofuran; hexane; various solvents; water; tert-butyl alcohol;
DOI:10.1021/ol015531m