1-(4-METHOXYPHENYL)-6-PHENYLHEXATRIENE

Base Information

Chemical Name:1-(4-METHOXYPHENYL)-6-PHENYLHEXATRIENE
CAS No.:3893-10-5
Molecular Formula:C19H18 O
Molecular Weight:262.35
Hs Code.:2909309090
Mol file:3893-10-5.mol

Synonyms:Anisole,p-(6-phenyl-1,3,5-hexatrienyl)-, (E,E,E)- (8CI); Benzene,1-methoxy-4-(6-phenyl-1,3,5-hexatrienyl)-, (E,E,E)-

Suppliers and Price of 1-(4-METHOXYPHENYL)-6-PHENYLHEXATRIENE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
1-(4-METHOXYPHENYL)-6-PHENYLHEXATRIENE 95.00%
5MG
$ 498.31

Total 4 raw suppliers

Chemical Property of 1-(4-METHOXYPHENYL)-6-PHENYLHEXATRIENE

Chemical Property:

Vapor Pressure:8E-08mmHg at 25°C
Melting Point:196-198 °C(lit.)
Refractive Index:1.63
Boiling Point:448.8°C at 760 mmHg
Flash Point:183.9°C
PSA：9.23000
Density:1.049g/cm³
LogP:4.97800
Solubility.:alcohols: soluble

Purity/Quality:

99% ^*data from raw suppliers

1-(4-METHOXYPHENYL)-6-PHENYLHEXATRIENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1-(4-METHOXYPHENYL)-6-PHENYLHEXATRIENE

There total 10 articles about 1-(4-METHOXYPHENYL)-6-PHENYLHEXATRIENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 100-59-4
phenylmagnesium chloride

: 194095-70-0
1-[(1E,3E,5E)-6-chlorohexa-1,3,5-trienyl]-4-methoxybenzene

: 3893-10-5
(1E,3E,5E)-1-(p-methoxyphenyl)-6-phenyl-1,3,5-hexatriene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; triethylamine; In tetrahydrofuran; at 20 ℃;
DOI:10.1016/S0040-4039(97)01156-8

Reference yield: 78.0%

: 699-19-4
4-methoxyphenylmagnesium chloride

: 194095-69-7
(1E,3E,5E)-1-chloro-6-phenylhexa-1,3,5-triene

: 3893-10-5
(1E,3E,5E)-1-(p-methoxyphenyl)-6-phenyl-1,3,5-hexatriene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; triethylamine; In tetrahydrofuran; for 4h;
DOI:10.1016/S0040-4020(99)00123-4

Reference yield:

: 194095-61-9
(5E)-6-chloro-1-(p-methoxyphenyl)hex-5-en-3-yn-1-ol

: 3893-10-5
(1E,3E,5E)-1-(p-methoxyphenyl)-6-phenyl-1,3,5-hexatriene

Guidance literature:: Multi-step reaction with 3 steps

1: 62 percent / Red-Al / diethyl ether; toluene / 5 h / -20 - 36 °C

2: 1.) methanesulfonyl chloride, triethylamine, 2.) DBU / 1.) CH₂Cl₂, room temperature, 30 min, 2.) CH₂Cl₂, room temperature

3: 82 percent / PdCl₂(PPh₃)2, triethylamine / tetrahydrofuran / 4 h

With bis-triphenylphosphine-palladium(II) chloride; methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; diethyl ether; toluene;
DOI:10.1016/S0040-4020(99)00123-4