Benzyl Trifluoromethanesulfinate

Base Information

• Chemical Name: Benzyl Trifluoromethanesulfinate
• CAS No.: 35896-45-8
• Molecular Formula: C₈H₇F₃O₂S
• Molecular Weight: 224.204
• Mol file: 35896-45-8.mol

Synonyms:Benzyl Trifluoromethanesulfinate

Chemical Property of Benzyl Trifluoromethanesulfinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzyl Trifluoromethanesulfinate

There total 5 articles about Benzyl Trifluoromethanesulfinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

benzyl bromide (100-39-0) + potassium triflinate (41804-89-1) → Benzyl Trifluoromethanesulfinate (35896-45-8)

Guidance literature:

iodide; In acetonitrile; in boiling acetonitrile, 6 h;

DOI:10.1021/ja00814a061

Reference yield: 90.0%

Benzyl Trifluoromethanesulfenate (66727-97-7) → Benzyl Trifluoromethanesulfinate (35896-45-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; a) 0 deg C, 1.5 h, b) room temp., 0.5 h;

Reference yield:

trifluoromethanesulfonic acid anhydride (1025373-45-8) + benzyl alcohol (100-51-6,185532-71-2) → Benzyl Trifluoromethanesulfinate (35896-45-8)

Guidance literature:

With chloro-trimethyl-silane; In toluene; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1021/acs.orglett.1c00688

upstream raw materials:

Benzyl Trifluoromethanesulfenate

silver trifluoromethanesulfinate

benzyl chloride

benzyl bromide

Downstream raw materials:

1-(ethoxymethyl)benzene

trifluoromethanesulfinic acid

benzyl methyl ether

Refernces

• 1、 Braverman, Samuel,Manor, Haim. "THE SYNTHESIS, SOLVOLYSIS AND REARRANGEMENT OF BENZYL TRIFLUOROMETHANESULFINATES". . p. 357 - 365. Retrieved 2007/10/02.