(1S,5R,6R)-6-(2-Benzyloxy-ethyl)-4,5-dimethyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene

Base Information

Chemical Name:(1S,5R,6R)-6-(2-Benzyloxy-ethyl)-4,5-dimethyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene
CAS No.:87413-14-7
Molecular Formula:C₁₆H₂₀O₃
Molecular Weight:260.333
Hs Code.:

Synonyms:(1S,5R,6R)-6-(2-Benzyloxy-ethyl)-4,5-dimethyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,5R,6R)-6-(2-Benzyloxy-ethyl)-4,5-dimethyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene

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Technology Process of (1S,5R,6R)-6-(2-Benzyloxy-ethyl)-4,5-dimethyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene

There total 1 articles about (1S,5R,6R)-6-(2-Benzyloxy-ethyl)-4,5-dimethyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 20843-07-6
3,4-dimethylfuran

: 19790-60-4
3-Benzyloxypropanal

: 87413-14-7
(1S,5R,6R)-6-(2-Benzyloxy-ethyl)-4,5-dimethyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene

Guidance literature:: In diethyl ether; benzene; for 6h; Irradiation;
DOI:10.1021/ja00327a020 DOI:10.1021/ja00360a035

Reference yield: 80.0%

: 87413-14-7
(1S,5R,6R)-6-(2-Benzyloxy-ethyl)-4,5-dimethyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: 87413-15-8
3-Chloro-benzoic acid (1R,3R,4S,5S,6R)-6-(2-benzyloxy-ethyl)-4-hydroxy-4,5-dimethyl-2,7-dioxa-bicyclo[3.2.0]hept-3-yl ester

Guidance literature:: With sodium hydrogencarbonate; In dichloromethane;
DOI:10.1021/ja00327a020 DOI:10.1021/ja00360a035

Reference yield:

: 87413-14-7
(1S,5R,6R)-6-(2-Benzyloxy-ethyl)-4,5-dimethyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene

: 87413-17-0
(4R,4aS,5S,6S,7aS)-4-(2-Benzyloxy-ethyl)-6-ethyl-2,2,4a,5-tetramethyl-tetrahydro-furo[2,3-d][1,3]dioxin-5-ol

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / NaHCO₃ / CH₂Cl₂

2: 3 N HCl / tetrahydrofuran

3: MgSO₄ / CH₂Cl₂

4: 2.) CuSO₄, CSA / 1.) THF, room temperature, 48 h

With hydrogenchloride; camphor-10-sulfonic acid; sodium hydrogencarbonate; magnesium sulfate; copper(II) sulfate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00360a035