(η5-2-methoxy-3-(diphenylhydroxymethyl)-6-phenylcyclohexadienyl)Mn(CO)3

Base Information

Chemical Name:(η5-2-methoxy-3-(diphenylhydroxymethyl)-6-phenylcyclohexadienyl)Mn(CO)3
CAS No.:898837-75-7
Molecular Formula:C₂₉H₂₃MnO₅
Molecular Weight:506.437
Hs Code.:

Synonyms:(η5-2-methoxy-3-(diphenylhydroxymethyl)-6-phenylcyclohexadienyl)Mn(CO)3

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Chemical Property of (η5-2-methoxy-3-(diphenylhydroxymethyl)-6-phenylcyclohexadienyl)Mn(CO)3

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Technology Process of (η5-2-methoxy-3-(diphenylhydroxymethyl)-6-phenylcyclohexadienyl)Mn(CO)3

There total 1 articles about (η5-2-methoxy-3-(diphenylhydroxymethyl)-6-phenylcyclohexadienyl)Mn(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 119-61-9
benzophenone

: 81857-39-8
(η5-2-methoxy-6-phenylcyclohexadienyl)Mn(CO)3

: 898837-75-7
(η5-2-methoxy-3-(diphenylhydroxymethyl)-6-phenylcyclohexadienyl)Mn(CO)3

Guidance literature:: With n-BuLi; In tetrahydrofuran; hexane; under N2; soln. of Mn complex in THF cooled to -78°C; soln. of n-BuLi in hexanes slowly added; stirred at -78°C; Ph2CO added; stirred at -78°C for 1 h; warmed to room temp.; quenched by addition of H2O; extd. with Et2O; combined org. layers washed with satd. aq. NaCl; dried (MgSO4); concd. in vac.; purified by flash chromy. (silica gel); elem. anal.;
DOI:10.1021/om7010529