RuCl(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2

Base Information

Chemical Name:RuCl(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2
CAS No.:339525-95-0
Molecular Formula:C₄₉H₃₉ClN₂P₂RuS
Molecular Weight:886.399
Hs Code.:

Synonyms:RuCl(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2

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Chemical Property of RuCl(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2

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Technology Process of RuCl(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2

There total 1 articles about RuCl(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: Hg((2-phenylazo)phenyl)2

: RuHCl(CS)(P(C₆H₅)3)2

: 339525-95-0
RuCl(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2

Guidance literature:: In toluene; byproducts: Hg, azobenzene, PPh3; Hg deriv. added to a susp. of Ru complex in toluene under N2; heated under reflux with stirring for 6 h; cooled, filtered to remove Hg, evapd., extd. with hot hexane to remove azobenzene and PPh3; purified by recrystn. from CH2Cl2-EtOH; identifird by elem. anal. and single crystal X-ray diffraction;
DOI:10.1016/S0022-328X(00)00692-6

Reference yield: 92.0%

: 339525-95-0
RuCl(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 339525-96-1
RuI(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2

Guidance literature:: With AgNO₃; In ethanol; dichloromethane; water; byproducts: AgCl; soln. of AgNO3 in H2O-EtOH added to soln. of Ru complex in CH2Cl2, stirred for 5 min, filtered to remove AgCl; soln. of NaI in H2O-EtOH added tothe filtrate, stirred for 10 min; evapd.; purified by recryst.n from CH2Cl2; identified by elem. anal. andsingle crystal X-ray diffraction;
DOI:10.1016/S0022-328X(00)00692-6

Reference yield: 87.0%

: 75-09-2
dichloromethane

: 339525-95-0
RuCl(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2

: 7647-15-6
sodium bromide

: RuBr(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2*0.5CH2Cl2

Guidance literature:: With AgNO₃; In ethanol; dichloromethane; water; byproducts: AgCl; soln. of AgNO3 in H2O-EtOH added to soln. of Ru complex in CH2Cl2, stirred for 5 min, filtered to remove AgCl; soln. of NaBr in H2O-EtOH added to the filtrate, stirred for 10 min; evapd.; purified by recrystn. from CH2Cl2; identified by elem. anal.;
DOI:10.1016/S0022-328X(00)00692-6