(permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)Cl

Base Information

• Chemical Name: (permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)Cl
• CAS No.: 173417-72-6
• Molecular Formula: C₄₄H₄₃ClFeP₂Ru
• Molecular Weight: 826.143
• Mol file: 173417-72-6.mol

Synonyms:(permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)Cl

Chemical Property of (permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)Cl

There total 1 articles about (permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + pentamethylcyclopentadienyl bis(triphenylphosphine)ruthenium(II) chloride (92361-49-4) → (permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)Cl (173417-72-6)

Guidance literature:

In benzene; N2-atmosphere; equimolar amts., refluxing for 2 h; collection (filtration), drying; can be recrystallized (PhMe); elem. anal.;

DOI:10.1016/0022-328X(95)05782-K

Reference yield: 78.0%

(permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)Cl (173417-72-6) → Cp*Ru(dppf)H (173417-71-5)

Guidance literature:

With Na(CH₃OH); In methanol; heating (reflux, 48 h); pptn. on cooling, filtrn. (N2), washing (MeOH), vac. drying, recrystn. (MeOH, benzene); elem. anal.;

DOI:10.1021/ja952206j

Reference yield: 76.0%

silver tetrafluoroborate (14104-20-2) + (permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)Cl (173417-72-6) + acetonitrile (75-05-8,26809-02-9) → [Ru(CH3CN)(permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)]BF4 (174904-29-1)

Guidance literature:

In acetone; N2-atmosphere; stirring Ru-complex with AgBF4 for 2 h, evapn., dissoln. in CH2Cl2, filtration, evapn., dissoln. in MeCN; addn. of ether, crystn. (refrigerator, overnight); elem. anal.;

DOI:10.1016/0022-328X(95)05782-K

upstream raw materials:

1,1'-bis-(diphenylphosphino)ferrocene

pentamethylcyclopentadienyl bis(triphenylphosphine)ruthenium(II) chloride

Downstream raw materials:

[(η(5)-C5Me5)Ru(1,1'-ferrocenyl-bis(diphenylphosphine))(MeCN)]PF6

Cp*Ru(dppf)H

[Ru(CH₃CN)(permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)]BF₄