(1S)-2-([tert-butyl(dimethyl)silyl]oxyimino)-1-methylethyl (3S)-3-[(4-methoxybenzyl)oxy] butanoate

Base Information

Chemical Name:(1S)-2-([tert-butyl(dimethyl)silyl]oxyimino)-1-methylethyl (3S)-3-[(4-methoxybenzyl)oxy] butanoate
CAS No.:861903-07-3
Molecular Formula:C₂₁H₃₅NO₅Si
Molecular Weight:409.598
Hs Code.:

Synonyms:(1S)-2-([tert-butyl(dimethyl)silyl]oxyimino)-1-methylethyl (3S)-3-[(4-methoxybenzyl)oxy] butanoate

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Chemical Property of (1S)-2-([tert-butyl(dimethyl)silyl]oxyimino)-1-methylethyl (3S)-3-[(4-methoxybenzyl)oxy] butanoate

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Technology Process of (1S)-2-([tert-butyl(dimethyl)silyl]oxyimino)-1-methylethyl (3S)-3-[(4-methoxybenzyl)oxy] butanoate

There total 3 articles about (1S)-2-([tert-butyl(dimethyl)silyl]oxyimino)-1-methylethyl (3S)-3-[(4-methoxybenzyl)oxy] butanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: C₉H₂₁NO₂Si

: 170649-30-6
(3S)-3-<(p-methoxybenzyl)-oxy>-butanoic acid

: 861903-07-3
(1S)-2-([tert-butyl(dimethyl)silyl]oxyimino)-1-methylethyl (3S)-3-[(4-methoxybenzyl)oxy] butanoate

Guidance literature:: With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃; for 12h;
DOI:10.1021/jo8016692

Reference yield:

: 861902-98-9
(2S)-2-[(4-methoxybenzyl)oxy]propanal O-[tert-butyl(dimethyl)silyl]oxime

: 861903-07-3
(1S)-2-([tert-butyl(dimethyl)silyl]oxyimino)-1-methylethyl (3S)-3-[(4-methoxybenzyl)oxy] butanoate

Guidance literature:: Multi-step reaction with 2 steps

1: DDQ; phosphate buffer / CH₂Cl₂ / 1 h / 20 °C / pH 7.0

2: 1.7 g / EDCI; DMAP / CH₂Cl₂ / 12 h / 20 °C

With dmap; phosphate buffer; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane;
DOI:10.1021/ol0508429

Reference yield:

: 41879-39-4
O-(tert-butyldimethylsilanyl)hydroxylamine

: 861903-07-3
(1S)-2-([tert-butyl(dimethyl)silyl]oxyimino)-1-methylethyl (3S)-3-[(4-methoxybenzyl)oxy] butanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / molecular sieves 4 Angstroem / CHCl₃ / 12 h / 20 °C

2: DDQ; phosphate buffer / CH₂Cl₂ / 1 h / 20 °C / pH 7.0

3: 1.7 g / EDCI; DMAP / CH₂Cl₂ / 12 h / 20 °C

With dmap; phosphate buffer; 4 A molecular sieve; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; chloroform;
DOI:10.1021/ol0508429