Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester

Base Information

Chemical Name:Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester
CAS No.:158189-03-8
Molecular Formula:C₁₆H₂₀O₄
Molecular Weight:276.332
Hs Code.:

Synonyms:Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester

Suppliers and Price of Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester

There total 5 articles about Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 65-85-0,8013-63-6
benzoic acid

: 158251-62-8
(S)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylprop-2-en-1-ol

: 158189-03-8
Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; for 2h; Ambient temperature;
DOI:10.1248/cpb.42.1328

Reference yield:

: 97971-43-2
Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-2-methyl-propyl ester

: 158189-03-8
Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / thionyl chloride / pyridine / 1 h / Ambient temperature

2: 81 percent / LiAlH₄ / diethyl ether / 0.75 h

3: 77 percent / diisopropyl azodicarboxylate, triphenylphosphine / tetrahydrofuran / 2 h / Ambient temperature

With lithium aluminium tetrahydride; thionyl chloride; di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; pyridine; diethyl ether;
DOI:10.1248/cpb.42.1328

Reference yield:

: 97971-44-3
Benzoic acid (S)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester

: 158189-03-8
Benzoic acid (R)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-allyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / LiAlH₄ / diethyl ether / 0.75 h

2: 77 percent / diisopropyl azodicarboxylate, triphenylphosphine / tetrahydrofuran / 2 h / Ambient temperature

With lithium aluminium tetrahydride; di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; diethyl ether;
DOI:10.1248/cpb.42.1328