(P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl⁽¹⁺⁾*BF₄^(1-)*1.5CH₂Cl₂=[(P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl]BF₄*1.5CH₂Cl₂

Base Information

• Chemical Name: (P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl⁽¹⁺⁾*BF₄^(1-)*1.5CH₂Cl₂=[(P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl]BF₄*1.5CH₂Cl₂
• CAS No.: 104321-47-3
• Molecular Formula: BF₄*CH₂Cl₂*C₆₂H₅₀ClNP₃Pt
• Molecular Weight: 1346.74

Synonyms:(P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl⁽¹⁺⁾*BF₄^(1-)*1.5CH₂Cl₂=[(P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl]BF₄*1.5CH₂Cl₂

Chemical Property of (P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl⁽¹⁺⁾*BF₄^(1-)*1.5CH₂Cl₂=[(P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl]BF₄*1.5CH₂Cl₂

Chemical Property:

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Technology Process of (P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl⁽¹⁺⁾*BF₄^(1-)*1.5CH₂Cl₂=[(P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl]BF₄*1.5CH₂Cl₂

There total 1 articles about (P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl⁽¹⁺⁾*BF₄^(1-)*1.5CH₂Cl₂=[(P(C₆H₅)3)2Pt(N(C₆H₄)C(P(C₆H₅)3)C(H))Cl]BF₄*1.5CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

silver tetrafluoroborate (14104-20-2) + cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1) + Triphenylphosphonium-indolylid-(3) (104292-28-6) → (P(C6H5)3)2Pt(N(C6H4)C(P(C6H5)3)C(H))Cl(1+)*BF4(1-)*1.5CH2Cl2=[(P(C6H5)3)2Pt(N(C6H4)C(P(C6H5)3)C(H))Cl]BF4*1.5CH2Cl2 (104321-47-3)

Guidance literature:

In dichloromethane; byproducts: AgCl; N2-atmosphere; addn. of 1 equiv. AgBF4 to Pt-complex, stirring (1 h), filtration off of AgCl, addn. of isonitrile (room temp.), stirring (1.5 h); concn., pptn. on Et2O addn., drying (vac.); elem. anal.;

Reference yield: 70.0%

(P(C6H5)3)2Pt(N(C6H4)C(P(C6H5)3)C(H))Cl(1+)*BF4(1-)*1.5CH2Cl2=[(P(C6H5)3)2Pt(N(C6H4)C(P(C6H5)3)C(H))Cl]BF4*1.5CH2Cl2 (104321-47-3) → (P(CH3)2C6H5)2Pt(CN(H)C6H4C(P(CH3)3))Cl(1+)*BF4(1-)*2CH2Cl2=[(P(CH3)2C6H5)2Pt(CN(H)C6H4C(P(CH3)3))Cl]BF4*2CH2Cl2 (104241-82-9)

Guidance literature:

With NEt₃; In dichloromethane; byproducts: [HNEt3]BF4; N2-atmosphere; stirring (room temp., 2 days); concn., pptn. on Et2O addn., filtration, drying (vac.); elem. anal.;

upstream raw materials:

silver tetrafluoroborate

cis-dichlorobis(triphenylphosphine)platinum(II)

Triphenylphosphonium-indolylid-⁽³⁾

Downstream raw materials:

(P(CH₃)2C₆H₅)2Pt(CN(H)C₆H₄C(P(CH₃)3))Cl⁽¹⁺⁾*BF₄^(1-)*2CH₂Cl₂=[(P(CH₃)2C₆H₅)2Pt(CN(H)C₆H₄C(P(CH₃)3))Cl]BF₄*2CH₂Cl₂

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