(diphenyl)ferrocene-ethynyl phosphine

Base Information

Chemical Name:(diphenyl)ferrocene-ethynyl phosphine
CAS No.:916074-56-1
Molecular Formula:C₂₄H₁₉FeP
Molecular Weight:394.236
Hs Code.:

Synonyms:(diphenyl)ferrocene-ethynyl phosphine

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Chemical Property of (diphenyl)ferrocene-ethynyl phosphine

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Technology Process of (diphenyl)ferrocene-ethynyl phosphine

There total 1 articles about (diphenyl)ferrocene-ethynyl phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 1271-47-2
ferroceneacetylene

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 916074-56-1
(diphenyl)ferrocene-ethynyl phosphine

Guidance literature:: With n-butyl lithium; In tetrahydrofuran; byproducts: LiCl; under Ar, Schlenk techniques; n-BuLi/hexane added dropwise to soln. of Fe complex in THF at -78°C, warmed to room temp., kept for 30 min,Ph2PCl added dropwise at -78°C, warmed, kept for 2 h at room tem p.; evapd. under vac., residue dissolved in CH2Cl2, soln. filtered, filtrateconcd., filtered over alumina using pentane as eluent, filtrate evapd.; elem. anal.;
DOI:10.1021/om0606892

Reference yield: 97.0%

: 916074-56-1
(diphenyl)ferrocene-ethynyl phosphine

: 162718-91-4
ClAu(tetrahydrothiophene)

: 1144033-41-9
[((diphenyl)ferrocene-ethynyl phosphine)AuCl]

Guidance literature:: In tetrahydrofuran; (N2); using Schlenk techniques; addn. dropwise soln. of (ferrocene-ethynyl)Ph2P to THF soln. containing of (THT)AuCl over a period of 1 h at 0°C; stirring at 25°C for 1 h; removal of all volatiles in vac., chromy. on silica gel with Et2O as eluent; elem. anal.;
DOI:10.1016/j.jorganchem.2008.11.046

Reference yield: 97.0%

: dichloro(p-cymene)ruthenium(II) dimer

: 75-09-2
dichloromethane

: 916074-56-1
(diphenyl)ferrocene-ethynyl phosphine

: [(C₅H₅)Fe(C₅H₄CCP(C₆H₅)2)RuCl₂(CH₃C₆H₄CH(CH₃)2)]*0.25CH₂Cl₂

Guidance literature:: In dichloromethane; under N2; stirred for 2 h; solvent removed (vac.), residue washed 5-6 times with diethyl ether, dried (vac.); elem. anal.;
DOI:10.1016/j.ica.2012.02.025