trans-3-(3,4-dimethylphenyl)-4-phenyl-1,2-dioxetane

Base Information

• Chemical Name: trans-3-(3,4-dimethylphenyl)-4-phenyl-1,2-dioxetane
• CAS No.: 135584-36-0
• Molecular Formula: C₁₈H₂₀O₂
• Molecular Weight: 268.356
• Mol file: 135584-36-0.mol

Synonyms:trans-3-(3,4-dimethylphenyl)-4-phenyl-1,2-dioxetane

Chemical Property of trans-3-(3,4-dimethylphenyl)-4-phenyl-1,2-dioxetane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of trans-3-(3,4-dimethylphenyl)-4-phenyl-1,2-dioxetane

There total 1 articles about trans-3-(3,4-dimethylphenyl)-4-phenyl-1,2-dioxetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-bromo-2-(3,4-dimethylphenyl)-3-phenyl-3-hydroperoxybutane (135584-34-8) → 3-(3,4-dimethylphenyl)-3-phenyl-2-butanone + trans-3-(3,4-dimethylphenyl)-4-phenyl-1,2-dioxetane (135584-36-0) + cis-3-(3,4-dimethylphenyl)-4-phenyl-1,2-dioxetane (135584-35-9)

Guidance literature:

With silver(I) acetate; In tetrachloromethane; at 0 ℃; for 1h;

DOI:10.1021/jo00021a033

Reference yield:

trans-3-(3,4-dimethylphenyl)-4-phenyl-1,2-dioxetane (135584-36-0) → acetophenone (98-86-2) + 3,4-dimethylacetophenone (3637-01-2)

Guidance literature:

With 2-methyl-but-2-ene; In o-xylene; at 60 ℃; Thermodynamic data; Rate constant; Mechanism; E_a, ΔH(excit.), ΔS(excit.);

DOI:10.1021/jo00021a033

upstream raw materials:

2-bromo-2-(3,4-dimethylphenyl)-3-phenyl-3-hydroperoxybutane

Downstream raw materials:

acetophenone

3,4-dimethylacetophenone