(E)-2-<(tert-butyl)dimethylsilyl>-2-<2'-(2'',6'',6''-trimethyl-2''-cyclohexenyl)vinyl>-1,3-dithiane

Base Information

Chemical Name:(E)-2-<(tert-butyl)dimethylsilyl>-2-<2'-(2'',6'',6''-trimethyl-2''-cyclohexenyl)vinyl>-1,3-dithiane
CAS No.:109629-47-2
Molecular Formula:C₂₁H₃₈S₂Si
Molecular Weight:382.75
Hs Code.:

Synonyms:(E)-2-<(tert-butyl)dimethylsilyl>-2-<2'-(2'',6'',6''-trimethyl-2''-cyclohexenyl)vinyl>-1,3-dithiane

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Chemical Property of (E)-2-<(tert-butyl)dimethylsilyl>-2-<2'-(2'',6'',6''-trimethyl-2''-cyclohexenyl)vinyl>-1,3-dithiane

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Technology Process of (E)-2-<(tert-butyl)dimethylsilyl>-2-<2'-(2'',6'',6''-trimethyl-2''-cyclohexenyl)vinyl>-1,3-dithiane

There total 5 articles about (E)-2-<(tert-butyl)dimethylsilyl>-2-<2'-(2'',6'',6''-trimethyl-2''-cyclohexenyl)vinyl>-1,3-dithiane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 37384-69-3
3-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-propenoic acid

: 109629-47-2
(E)-2-<(tert-butyl)dimethylsilyl>-2-<2'-(2'',6'',6''-trimethyl-2''-cyclohexenyl)vinyl>-1,3-dithiane

Guidance literature:: Multi-step reaction with 4 steps

1: LiAlH₄ / diethyl ether / 0.5 h / Ambient temperature

2: MnO₂ / hexane

3: BF₃*Et₂O / acetic acid; CH₂Cl₂ / 1.) 0 deg C, 45 min, 2.) room temperature, 3 h

4: 1.) BuLi / 1.) THF, HMPA, hexane, 1 h, 2.) THF, room temperature, 1 h

With manganese(IV) oxide; lithium aluminium tetrahydride; n-butyllithium; boron trifluoride diethyl etherate; In diethyl ether; hexane; dichloromethane; acetic acid;
DOI:10.1002/hlca.19860690612

Reference yield:

: 127-41-3,6901-97-9,14398-36-8,24190-29-2,30685-95-1,31798-12-6,52340-45-1,67529-94-6,67529-95-7
alpha-ionone

: 109629-47-2
(E)-2-<(tert-butyl)dimethylsilyl>-2-<2'-(2'',6'',6''-trimethyl-2''-cyclohexenyl)vinyl>-1,3-dithiane

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) I₂, 2.) 2N NaOH / 1.) pyridine, 100 deg C, 1 h, 2.) 100 deg C

2: LiAlH₄ / diethyl ether / 0.5 h / Ambient temperature

3: MnO₂ / hexane

4: BF₃*Et₂O / acetic acid; CH₂Cl₂ / 1.) 0 deg C, 45 min, 2.) room temperature, 3 h

5: 1.) BuLi / 1.) THF, HMPA, hexane, 1 h, 2.) THF, room temperature, 1 h

With manganese(IV) oxide; sodium hydroxide; lithium aluminium tetrahydride; n-butyllithium; boron trifluoride diethyl etherate; iodine; In diethyl ether; hexane; dichloromethane; acetic acid;
DOI:10.1002/hlca.19860690612

Reference yield:

: 51768-75-3
(E)-3-(2,6,6-trimethylcyclohex-2-enyl)prop-2-en-1-ol

: 109629-47-2
(E)-2-<(tert-butyl)dimethylsilyl>-2-<2'-(2'',6'',6''-trimethyl-2''-cyclohexenyl)vinyl>-1,3-dithiane

Guidance literature:: Multi-step reaction with 3 steps

1: MnO₂ / hexane

2: BF₃*Et₂O / acetic acid; CH₂Cl₂ / 1.) 0 deg C, 45 min, 2.) room temperature, 3 h

3: 1.) BuLi / 1.) THF, HMPA, hexane, 1 h, 2.) THF, room temperature, 1 h

With manganese(IV) oxide; n-butyllithium; boron trifluoride diethyl etherate; In hexane; dichloromethane; acetic acid;
DOI:10.1002/hlca.19860690612