Technology Process of 3-(2,6-diisopropylphenyl)-11-((9-(pyridin-2-yl)-9H-carbazol-2-yl)oxy)imidazo[1,2-f]phenanthridine
There total 11 articles about 3-(2,6-diisopropylphenyl)-11-((9-(pyridin-2-yl)-9H-carbazol-2-yl)oxy)imidazo[1,2-f]phenanthridine which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
2-Picolinic acid; potassium phosphate; copper(l) iodide;
In
dimethyl sulfoxide;
at 150 ℃;
for 16h;
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: potassium phosphate monohydrate / bis-triphenylphosphine-palladium(II) chloride / toluene; water / 15.5 h / Inert atmosphere
2.1: isopropyl alcohol / 24 h / Reflux
2.2: 24 h / 60 °C / Reflux
3.1: potassium phosphate monohydrate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium(0) / toluene; water / 18 h / Reflux
4.1: hydrogen / palladium 10% on activated carbon; platinum on carbon / ethanol / 12 h / 2585.81 Torr / Inert atmosphere
5.1: boron tribromide / dichloromethane / 18 h / -78 - 20 °C
6.1: potassium phosphate; copper(l) iodide; 2-Picolinic acid / dimethyl sulfoxide / 16 h / 150 °C
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; 2-Picolinic acid; potassium phosphate; copper(l) iodide; potassium phosphate monohydrate; hydrogen; boron tribromide;
bis-triphenylphosphine-palladium(II) chloride; tris-(dibenzylideneacetone)dipalladium(0); palladium 10% on activated carbon; platinum on carbon;
In
ethanol; dichloromethane; water; dimethyl sulfoxide; isopropyl alcohol; toluene;
- Guidance literature:
-
Multi-step reaction with 4 steps
1: potassium phosphate monohydrate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium(0) / toluene; water / 18 h / Reflux
2: hydrogen / palladium 10% on activated carbon; platinum on carbon / ethanol / 12 h / 2585.81 Torr / Inert atmosphere
3: boron tribromide / dichloromethane / 18 h / -78 - 20 °C
4: potassium phosphate; copper(l) iodide; 2-Picolinic acid / dimethyl sulfoxide / 16 h / 150 °C
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; 2-Picolinic acid; potassium phosphate; copper(l) iodide; potassium phosphate monohydrate; hydrogen; boron tribromide;
tris-(dibenzylideneacetone)dipalladium(0); palladium 10% on activated carbon; platinum on carbon;
In
ethanol; dichloromethane; water; dimethyl sulfoxide; toluene;
