Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate

Base Information

• Chemical Name: Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
• CAS No.: 32679-02-0
• Molecular Formula: C12H18BF4N2Rh
• Molecular Weight: 379.99
• European Community (EC) Number: 626-274-7
• DSSTox Substance ID: DTXSID60456403
• Mol file: 32679-02-0.mol

Synonyms:32679-02-0;Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate;[rh(cod)(mecn)2]bf4;bis(acetonitrile)(1,5-cyclooctadiene)rhodium(i) tetrafluoroborate;Bis(acetonitrile)(1,5-cyclooctadiene) Rhodium(1) tetrafluoroborate;acetonitrile;(1Z,5Z)-cycloocta-1,5-diene;rhodium;tetrafluoroborate;DTXSID60456403;ZIBLHOBPBGAKNV-SUESZSCISA-N;32679-02-0 (name error);MFCD06798085;AKOS016006206;J-018832;bis(acetonitrile) (1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Chemical Property of Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate

Chemical Property:

• PSA: 47.58000
• LogP: 5.03256
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: Air Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 380.05541
• Heavy Atom Count: 20
• Complexity: 121

Purity/Quality:

97% ^*data from raw suppliers

BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [B-](F)(F)(F)F.CC#N.CC#N.C1CC=CCCC=C1.[Rh]
• Isomeric SMILES: [B-](F)(F)(F)F.CC#N.CC#N.C1/C=C\CC/C=C\C1.[Rh]
• Uses: Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate [Rh(cod)(MeCN)2]BF4 may be used as a catalyst for the rhodium(I)-catalyzed silylation of aryl iodides and bromides with tetraethoxysilanes to form aryl silanes such as (4-bromophenyl)triethoxysilane and 4-(triethoxysilyl)acetophenone.

Technology Process of Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate

There total 5 articles about Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + silver tetrafluoroborate (14104-20-2) → bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (32679-02-0)

Guidance literature:

In acetonitrile; byproducts: AgCl; addn. of AgBF4 to soln. of Rh-compd., pptn. of AgCl, stirring for 15 min.; filtration of pptd. AgCl, evapn.;

DOI:10.1016/S0020-1693(00)80580-0

Reference yield: 49.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + trityl tetrafluoroborate (341-02-6) + acetonitrile (75-05-8,26809-02-9) → bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (32679-02-0)

Guidance literature:

In dichloromethane; under Ar; CH2Cl2 added to mixt. of Rh complex and Ph3CBF4, added acetonitrile; concd. in vac., pptd. by addn. of Et2O, filtered, washed with Et2O;

DOI:10.1021/ja00363a014

Reference yield:

silver tetrafluoroborate (14104-20-2) + chloro(1,5-cyclooctadiene)rhodium(I) dimer + acetonitrile (75-05-8,26809-02-9) → bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (32679-02-0)

Guidance literature:

at 20 ℃; for 1h;

DOI:10.1002/ejic.201900317

upstream raw materials:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

trityl tetrafluoroborate

acetonitrile

silver tetrafluoroborate

Downstream raw materials:

cis-[Rh(cod)((diphenylphosphanyl)methanol)2]BF₄

[Rh(N,N'-bis(diphenylphosphino)-1,1-dimethyl-N,N'-di-p-tolyl-silanediamine)(1,5-cyclooctadiene)]BF₄

[rhodium(I)(1,5-cyclooctadiene)(1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene)](tetrafluoroborate)

[rhodium(I)(1,5-cyclooctadiene)(1,4-bis(2,4,6-trimethylphenyl)-1,4-diaza-1,3-butadiene)](tetrafluoroborate)

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 32679-02-0 BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE

Send

Send

Metric Ton KG G Pound L ML

Send

Send