Technology Process of 4-methyl-3,5-bis(perfluorohexyl)benzyl thioacetate
There total 4 articles about 4-methyl-3,5-bis(perfluorohexyl)benzyl thioacetate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
di-isopropyl azodicarboxylate; triphenylphosphine;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 3h;
Inert atmosphere;
DOI:10.1002/ejoc.201100638
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: iodine; copper / N,N-dimethyl-formamide; acetone / 95 °C / Inert atmosphere
1.2: 95 - 125 °C / Inert atmosphere
2.1: lithium aluminium tetrahydride / diethyl ether / 12 h / 20 °C / Inert atmosphere
3.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 3 h / 0 - 20 °C / Inert atmosphere
With
lithium aluminium tetrahydride; di-isopropyl azodicarboxylate; iodine; copper; triphenylphosphine;
In
tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; acetone;
3.1: modified Mitsunobu reaction;
DOI:10.1002/ejoc.201100638
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: iodine; copper / N,N-dimethyl-formamide; acetone / 95 °C / Inert atmosphere
1.2: 95 - 125 °C / Inert atmosphere
2.1: lithium aluminium tetrahydride / diethyl ether / 12 h / 20 °C / Inert atmosphere
3.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 3 h / 0 - 20 °C / Inert atmosphere
With
lithium aluminium tetrahydride; di-isopropyl azodicarboxylate; iodine; copper; triphenylphosphine;
In
tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; acetone;
3.1: modified Mitsunobu reaction;
DOI:10.1002/ejoc.201100638
