{Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)={Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}BF₄

Base Information

• Chemical Name: {Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)={Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}BF₄
• CAS No.: 70196-23-5
• Molecular Formula: BF₄*C₅₆H₅₆P₄Rh
• Molecular Weight: 1042.67

Synonyms:{Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)={Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}BF₄

Chemical Property of {Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)={Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}BF₄

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Technology Process of {Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)={Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}BF₄

There total 5 articles about {Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)={Rh((C₆H₅)2PCH₂CH₂CH₂CH₂P(C₆H₅)2)2}BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

[,14-bis(diphenylphosphino)butane] (1,5-cyclooctadiene)rhodium(I) tetrafluoroborate + 1,4-di(diphenylphosphino)-butane (7688-25-7) → {Rh((C6H5)2PCH2CH2CH2CH2P(C6H5)2)2}(1+)*BF4(1-)={Rh((C6H5)2PCH2CH2CH2CH2P(C6H5)2)2}BF4 (70196-23-5)

Guidance literature:

In methanol; dichloromethane; H2-atmosphere; stirring (room temp., 20 min), phosphine soln. (CH2Cl2) addn., stirring (2 h); evapn. (vac.);

DOI:10.1021/om960112s

Reference yield: 91.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + silver tetrafluoroborate (14104-20-2) + 1,4-di(diphenylphosphino)-butane (7688-25-7) → {Rh((C6H5)2PCH2CH2CH2CH2P(C6H5)2)2}(1+)*BF4(1-)={Rh((C6H5)2PCH2CH2CH2CH2P(C6H5)2)2}BF4 (70196-23-5)

Guidance literature:

With hydrogen; In methanol; dichloromethane; acetone; H2-atmosphere, room temp.; evapn. (vac.), recrystn. (CH2Cl2 / n-pentane);

DOI:10.1021/om960112s

Reference yield:

acethylacetonato(1,5-cyclooctadiene)rhodium(I) + 1,4-di(diphenylphosphino)-butane (7688-25-7) → {Rh((C6H5)2PCH2CH2CH2CH2P(C6H5)2)2}(1+)*BF4(1-)={Rh((C6H5)2PCH2CH2CH2CH2P(C6H5)2)2}BF4 (70196-23-5)

Guidance literature:

With trityl tetrafluoroborate; In dichloromethane; to a soln. of the Rh complex in CH2Cl2, a soln. of the appropriate amt. of Ph2P(CH2)4PPh2 is added at 0°C; soln. concd. in vac., addn. of Et2O, compd. sepd.; recrystd. from dichloromethane/ether;

DOI:10.1016/0022-328X(85)87071-6

upstream raw materials:

1,4-di(diphenylphosphino)-butane

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

silver tetrafluoroborate

Downstream raw materials:

Rh(((C₆H₅)2PCH₂CH₂)2)2⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Rh(((C₆H₅)2PC₂H₄)2)2][B(C₆H₅)4]

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