pentadecachloro-3-ethoxy(diphenylmethylene)cyclohexa-1,4-diene

Base Information

• Chemical Name: pentadecachloro-3-ethoxy(diphenylmethylene)cyclohexa-1,4-diene
• CAS No.: 82891-69-8
• Molecular Formula: C₂₁H₅Cl₁₅O
• Molecular Weight: 805.065
• Mol file: 82891-69-8.mol

Synonyms:pentadecachloro-3-ethoxy(diphenylmethylene)cyclohexa-1,4-diene

Chemical Property of pentadecachloro-3-ethoxy(diphenylmethylene)cyclohexa-1,4-diene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of pentadecachloro-3-ethoxy(diphenylmethylene)cyclohexa-1,4-diene

There total 1 articles about pentadecachloro-3-ethoxy(diphenylmethylene)cyclohexa-1,4-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.7%

ethanol (64-17-5) + perchlorotriphenylcarbenium hexachloroantimonate (30482-37-2) → pentadecachloro-3-ethoxy(diphenylmethylene)cyclohexa-1,4-diene (82891-69-8)

Guidance literature:

for 0.5h; Irradiation;

DOI:10.1021/jo00144a019

Reference yield: 95.7%

pentadecachloro-3-ethoxy(diphenylmethylene)cyclohexa-1,4-diene (82891-69-8) → perchlorofuchsone, perchloro(diphenylmethylene)cyclohexa-2,5-dienone (29972-98-3)

Guidance literature:

at 100 ℃; for 2h;

DOI:10.1021/jo00144a019

Reference yield:

pentadecachloro-3-ethoxy(diphenylmethylene)cyclohexa-1,4-diene (82891-69-8) → 4-(bromoacetoxy)tetradecachlorotriphenylmethyl radical (82891-71-2)

Guidance literature:

Multi-step reaction with 3 steps

1: 95.7 percent / 2 h / 100 °C

2: 99.6 percent / aq. HI, I₂ / benzene / 24 h

3: 92.2 percent / triethylamine / 1 h / Heating

With hydrogen iodide; iodine; triethylamine; In benzene;

DOI:10.1021/jo00144a019

upstream raw materials:

ethanol

perchlorotriphenylcarbenium hexachloroantimonate

Downstream raw materials:

perchlorofuchsone, perchloro(diphenylmethylene)cyclohexa-2,5-dienone

bis(2,3,4,5,6-pentachlorophenyl)(2,3,5,6-tetrachloro-4-hydroxyphenyl)methyl radical

Tetradecachloro-4-<(ethoxycarbonyl)oxy>triphenylmethyl radical

tetradecachloro-4-methoxytriphenylmethyl radical