7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone

Base Information

Chemical Name:7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone
CAS No.:70629-87-7
Molecular Formula:C₃₆H₃₁F₃N₂O₁₄
Molecular Weight:772.642
Hs Code.:

Synonyms:7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone

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Chemical Property of 7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone

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Technology Process of 7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone

There total 15 articles about 7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 21794-55-8
(+)-Daunomycinone

: 76793-37-8
1-O-acetyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranose

: 70629-87-7
7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone

Guidance literature:: With toluene-4-sulfonic acid; In dichloromethane; benzene; at 20 ℃; for 2h;
DOI:10.1016/S0008-6215(00)84673-X

Reference yield: 31.0%

: 21794-55-8
(+)-Daunomycinone

: 72384-25-9,73891-04-0,73891-07-3,76793-53-8,76793-57-2,77398-05-1,98103-08-3
1,5-anhydro-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-D-arabino-hex-1-enitol

: 70629-87-7
7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone

: 70629-86-6
7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-D-arabino-hexopyranosyl)daunomycinone

Guidance literature:: With toluene-4-sulfonic acid; In dichloromethane; benzene; at 50 ℃; for 1h;
DOI:10.1016/S0008-6215(00)84673-X

Reference yield:

: 76739-66-7
3,4-di-O-acetyl-D-rhamnal

: 70629-87-7
7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) sodium azide ; 2.) lithium aluminium hydride / 1.) bortrifluorid etherate / 1.) acetonitrile; 2.) ether

2: 2.) pyridine

3: 21 percent / p-toluenesulfonic acid / benzene; CH₂Cl₂ / 1 h / 50 °C

With pyridine; lithium aluminium tetrahydride; sodium azide; toluene-4-sulfonic acid; boron trifluoride diethyl etherate; In dichloromethane; benzene;
DOI:10.1016/S0008-6215(00)84673-X