cis-[(PPh₃)2Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃*Et₂O

Base Information

• Chemical Name: cis-[(PPh₃)2Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃*Et₂O
• CAS No.: 1331786-52-7
• Molecular Formula: C₄H₁₀O*C₄₈H₄₁N₄OP₂Pt*NO₃
• Molecular Weight: 1083.03

Synonyms:cis-[(PPh₃)2Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃*Et₂O

Chemical Property of cis-[(PPh₃)2Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃*Et₂O

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Technology Process of cis-[(PPh₃)2Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃*Et₂O

There total 3 articles about cis-[(PPh₃)2Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide^(1-))]NO₃*Et₂O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1-MeCyt (1122-47-0) + diethyl ether (60-29-7,927820-24-4) + cis-[(PPh3)2Pt(μ-OH)]2(NO3)2 + benzonitrile (100-47-0) → cis-[(PPh3)2Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide(1-))]NO3*Et2O (1331786-52-7)

Guidance literature:

In benzonitrile; mixt. of Pt complex and 1-methylcytosine in PhCN stirred at room temp. for ca. 4 h; filtered; Et2O added to filtrate; solid isolated; dried under vac.; elem. anal.;

DOI:10.1021/ic901508w

Reference yield:

(Z)-N-(1-methyl-2-oxo-1,2-dihydropyramidin-4-yl)benzimidamide (1331786-53-8) → cis-[(PPh3)2Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide(1-))]NO3*Et2O (1331786-52-7)

Guidance literature:

Multi-step reaction with 2 steps

1: chloroform-d1

2: proton sponge / chloroform-d1

With proton sponge; In chloroform-d1;

DOI:10.1039/c1dt10638d

Reference yield:

cis-[(PPh3)2PtNH=C(Ph)(1-methylcytosine(-H))](1+) → cis-[(PPh3)2Pt(9-N-(1-methyl-2-oxo-2,3-dihydropyrimidin-4(1H)-ylidene)benzimidamide(1-))]NO3*Et2O (1331786-52-7)

Guidance literature:

With proton sponge; In chloroform-d1; identified by NMR;

DOI:10.1039/c1dt10638d

upstream raw materials:

1-MeCyt

diethyl ether

benzonitrile

(Z)-N-(1-methyl-2-oxo-1,2-dihydropyramidin-4-yl)benzimidamide

Downstream raw materials:

cis-dichlorobis(triphenylphosphine)platinum(II)

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