dibutyl (2-O-acetyl-3,4-di-O-benzyl-α-D-mannopyranosyl) phosphate

Base Information

• Chemical Name: dibutyl (2-O-acetyl-3,4-di-O-benzyl-α-D-mannopyranosyl) phosphate
• CAS No.: 943837-13-6
• Molecular Formula: C₃₀H₄₃O₁₀P
• Molecular Weight: 594.639
• Mol file: 943837-13-6.mol

Synonyms:dibutyl (2-O-acetyl-3,4-di-O-benzyl-α-D-mannopyranosyl) phosphate

Chemical Property of dibutyl (2-O-acetyl-3,4-di-O-benzyl-α-D-mannopyranosyl) phosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dibutyl (2-O-acetyl-3,4-di-O-benzyl-α-D-mannopyranosyl) phosphate

There total 1 articles about dibutyl (2-O-acetyl-3,4-di-O-benzyl-α-D-mannopyranosyl) phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

3,4-O-benzyl α-D-mannopyranose 1,2,6-orthoacetate + dibutyl phosphate (107-66-4) → dibutyl (2-O-acetyl-3,4-di-O-benzyl-α-D-mannopyranosyl) phosphate (943837-13-6)

Guidance literature:

In acetonitrile; at 120 ℃; for 0.0833333h; Inert atmosphere; Molecular sieve; Microwave irradiation;

DOI:10.1039/b804069a

Reference yield: 94.0%

dibutyl (2-O-acetyl-3,4-di-O-benzyl-α-D-mannopyranosyl) phosphate (943837-13-6) + (fluorenylmethoxy)carbonyl chloride (28920-43-6) → dibutyl 2-O-acetyl-3,4-di-O-benzyl-6-O-(9-fluorenylmethoxycarbonyl)-α-D-mannopyranoside phosphate (943837-16-9)

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1080/07328300701298204

Reference yield: 93.0%

dibutyl (2-O-acetyl-3,4-di-O-benzyl-α-D-mannopyranosyl) phosphate (943837-13-6) + 2-azido-2-methylpropanoic anhydride (404942-30-9) → dibutyl 2-O-acetyl-6-O-(2-azido-2-methylpropanoyl)-3,4-di-O-benzyl-α-D-mannopyranoside phosphate

Guidance literature:

With pyridine; dmap; In dichloromethane; at 20 ℃; for 3h;

DOI:10.1080/07328300701298204

upstream raw materials:

dibutyl phosphate

Downstream raw materials:

dibutyl 2-O-acetyl-3,4-di-O-benzyl-6-O-triisopropylsilyl-α-D-mannopyranoside phosphate

dibutyl 2-O-acetyl-3,4-di-O-benzyl-6-O-(9-fluorenylmethoxycarbonyl)-α-D-mannopyranoside phosphate