[5,15-bis[3,5-di(tert-butyl)phenyl]-1,10-diiodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Base Information

• Chemical Name: [5,15-bis[3,5-di(tert-butyl)phenyl]-1,10-diiodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)
• CAS No.: 866321-86-0
• Molecular Formula: C₄₈H₅₀I₂N₄Zn
• Molecular Weight: 1002.15

Synonyms:[5,15-bis[3,5-di(tert-butyl)phenyl]-1,10-diiodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Chemical Property of [5,15-bis[3,5-di(tert-butyl)phenyl]-1,10-diiodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

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Technology Process of [5,15-bis[3,5-di(tert-butyl)phenyl]-1,10-diiodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

There total 3 articles about [5,15-bis[3,5-di(tert-butyl)phenyl]-1,10-diiodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (187387-14-0) → [5,15-bis[3,5-di(tert-butyl)phenyl]-1,10-diiodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) (866321-86-0)

Guidance literature:

With pyridine; iodine; bis-[(trifluoroacetoxy)iodo]benzene; In chloroform; at 20 ℃; for 1.25h; Darkness;

DOI:10.1039/c8ob00491a

Reference yield: 63.0%

[5,15-bis[3,5-di(tert-butyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) + iodine (7553-56-2,12190-71-5,8031-47-8) → [5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) (220355-76-0) + [5,15-bis[3,5-di(tert-butyl)phenyl]-1,10-diiodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) (866321-86-0)

Guidance literature:

With AgPF₆; In pyridine; chloroform; acetonitrile; N2 atm.; a soln. of AgPF6 in CH3CN was added at 25°C to a soln. of complex and I2 in CHCl3/pyridine 30:1, 13 min; H2O was added, the organic layer was washed with H2O, dried (Na2SO4), evapd. in vac., flash chromy. (silica gel; cyclohexane/CH2Cl2 1:1. 1% v/v (C2H5)3N);

DOI:10.1002/hlca.200590144

Reference yield:

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (187387-14-0) + iodine (7553-56-2,12190-71-5,8031-47-8) → [5,15-bis[3,5-di(tert-butyl)phenyl]-1,10-diiodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) (866321-86-0)

Guidance literature:

With AgPF₆; In chloroform; prepn. according to A. Nakano et al., Tetrahedron Lett., 1998, 39, 9489;D. Bonifazi et al., Helv. Chim. Acta, 2005, 88, 1839; room temp.; isolated by flash column chromy. on silica gel;

DOI:10.1039/b820210a

upstream raw materials:

iodine

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

Downstream raw materials:

[5,15-bis(3-cyanophenyl)-10,20-bis[3,5-di(tert-butyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Zn(C₂₀H₈N₄(C₆H₄N(CH₃)2)2(C₆H₃(C(CH₃)3)2)2)

Zn(C₂₀H₈N₄(C₁₄H₉)2(C₆H₃(C(CH₃)3)2)2)

Zn(C₂₀H₈N₄(C₁₄H₈C₆H₄N(CH₃)2)2(C₆H₃(C(CH₃)3)2)2)

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