ethyl 2-(1'-(4''-bromophenyl)-1'(E)-propen-2'-yl)-2-methyl-4-pentenoate

Base Information

Chemical Name:ethyl 2-(1'-(4''-bromophenyl)-1'(E)-propen-2'-yl)-2-methyl-4-pentenoate
CAS No.:1042097-00-6
Molecular Formula:C₁₇H₂₁BrO₂
Molecular Weight:337.257
Hs Code.:

Synonyms:ethyl 2-(1'-(4''-bromophenyl)-1'(E)-propen-2'-yl)-2-methyl-4-pentenoate

Suppliers and Price of ethyl 2-(1'-(4''-bromophenyl)-1'(E)-propen-2'-yl)-2-methyl-4-pentenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ethyl 2-(1'-(4''-bromophenyl)-1'(E)-propen-2'-yl)-2-methyl-4-pentenoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ethyl 2-(1'-(4''-bromophenyl)-1'(E)-propen-2'-yl)-2-methyl-4-pentenoate

There total 2 articles about ethyl 2-(1'-(4''-bromophenyl)-1'(E)-propen-2'-yl)-2-methyl-4-pentenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 676-58-4
methylmagnesium chloride

: 106-95-6
allyl bromide

: 189626-02-6
ethyl 4-(p-bromophenyl)-2-methyl-2,3-butadienoate

: 1042097-00-6
ethyl 2-(1'-(4''-bromophenyl)-1'(E)-propen-2'-yl)-2-methyl-4-pentenoate

Guidance literature:: methylmagnesium chloride; ethyl 4-(p-bromophenyl)-2-methyl-2,3-butadienoate; With iron(III) chloride hexahydrate; In tetrahydrofuran; toluene; at -78 - 20 ℃; Inert atmosphere;

allyl bromide; With copper(l) iodide; In tetrahydrofuran; toluene; Inert atmosphere;

With ammonium chloride; In tetrahydrofuran; water; toluene; at 0 - 20 ℃; stereoselective reaction;
DOI:10.1002/adsc.200900091

Reference yield:

: 591-87-7
Allyl acetate

: 676-58-4
methylmagnesium chloride

: 189626-02-6
ethyl 4-(p-bromophenyl)-2-methyl-2,3-butadienoate

: ethyl 4-(4'-bromophenyl)-2,3-dimethyl-3-butenoate

: 1042096-83-2
ethyl 2-(1'-(4''-bromophenyl)-1'(Z)-propen-2'-yl)-2-methyl-4-pentenoate

: 1042097-00-6
ethyl 2-(1'-(4''-bromophenyl)-1'(E)-propen-2'-yl)-2-methyl-4-pentenoate

Guidance literature:: methylmagnesium chloride; ethyl 4-(p-bromophenyl)-2-methyl-2,3-butadienoate; With iron(III)-acetylacetonate; In tetrahydrofuran; toluene; at -78 ℃; for 1h; Inert atmosphere;

Allyl acetate; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; toluene; at -78 - 20 ℃; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ol8012815