bis[4-tert-butyl-2,6-bis(2,2,2-trifluoroethoxymethyl)phenyl] disulfide

Base Information

Chemical Name:bis[4-tert-butyl-2,6-bis(2,2,2-trifluoroethoxymethyl)phenyl] disulfide
CAS No.:1259293-82-7
Molecular Formula:C₃₂H₃₈F₁₂O₄S₂
Molecular Weight:778.764
Hs Code.:

Synonyms:bis[4-tert-butyl-2,6-bis(2,2,2-trifluoroethoxymethyl)phenyl] disulfide

Suppliers and Price of bis[4-tert-butyl-2,6-bis(2,2,2-trifluoroethoxymethyl)phenyl] disulfide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of bis[4-tert-butyl-2,6-bis(2,2,2-trifluoroethoxymethyl)phenyl] disulfide

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of bis[4-tert-butyl-2,6-bis(2,2,2-trifluoroethoxymethyl)phenyl] disulfide

There total 3 articles about bis[4-tert-butyl-2,6-bis(2,2,2-trifluoroethoxymethyl)phenyl] disulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 75-89-8
2,2,2-trifluoroethanol

: 1259294-21-7
bis[2,6-bis(bromomethyl)-4-tert-butylphenyl] disulfide

: 1259293-82-7
bis[4-tert-butyl-2,6-bis(2,2,2-trifluoroethoxymethyl)phenyl] disulfide

Guidance literature:: 2,2,2-trifluoroethanol; With sodium; at 70 ℃; Inert atmosphere;

bis[2,6-bis(bromomethyl)-4-tert-butylphenyl] disulfide; In toluene; at 110 ℃; for 24h; Inert atmosphere;
DOI:10.1021/ja106343h

Reference yield:

: 5345-05-1
4-t-butyl-2,6-dimethylbromobenzene

: 1259293-82-7
bis[4-tert-butyl-2,6-bis(2,2,2-trifluoroethoxymethyl)phenyl] disulfide

Guidance literature:: Multi-step reaction with 4 steps

1.1: bromine / 5.5 h / 130 °C / Inert atmosphere

1.2: 100 °C / Inert atmosphere

2.1: iodine; magnesium / tetrahydrofuran / 2 h / Reflux; Inert atmosphere

2.2: 2 h / Cooling with ice; Reflux; Inert atmosphere

2.3: Cooling with ice

3.1: hydrogen bromide; acetic acid / 4 h / 65 °C

4.1: sodium / 70 °C / Inert atmosphere

4.2: 24 h / 110 °C / Inert atmosphere

With hydrogen bromide; bromine; iodine; sodium; magnesium; acetic acid; In tetrahydrofuran;
DOI:10.1021/ja106343h

Reference yield:

: 287969-13-5
2-bromo-5-tert-butyl-1,3-bis(methoxymethyl)benzene

: 1259293-82-7
bis[4-tert-butyl-2,6-bis(2,2,2-trifluoroethoxymethyl)phenyl] disulfide

Guidance literature:: Multi-step reaction with 3 steps

1.1: iodine; magnesium / tetrahydrofuran / 2 h / Reflux; Inert atmosphere

1.2: 2 h / Cooling with ice; Reflux; Inert atmosphere

1.3: Cooling with ice

2.1: hydrogen bromide; acetic acid / 4 h / 65 °C

3.1: sodium / 70 °C / Inert atmosphere

3.2: 24 h / 110 °C / Inert atmosphere

With hydrogen bromide; iodine; sodium; magnesium; acetic acid; In tetrahydrofuran;
DOI:10.1021/ja106343h