(2R,3S)-2-Phenyl-3-(propan-2-yl)oxirane

Base Information

Chemical Name:(2R,3S)-2-Phenyl-3-(propan-2-yl)oxirane
CAS No.:94719-34-3
Molecular Formula:C11H14O
Molecular Weight:162.232
Hs Code.:2910900090
DSSTox Substance ID:DTXSID00539229
Wikidata:Q82414928
Mol file:94719-34-3.mol

Synonyms:94719-34-3;DTXSID00539229;(2R,3S)-2-Phenyl-3-(propan-2-yl)oxirane

Suppliers and Price of (2R,3S)-2-Phenyl-3-(propan-2-yl)oxirane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (2R,3S)-2-Phenyl-3-(propan-2-yl)oxirane

Chemical Property:

PSA：12.53000
LogP:2.78250
XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:162.104465066
Heavy Atom Count:12
Complexity:147

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)C1C(O1)C2=CC=CC=C2
Isomeric SMILES:CC(C)[C@H]1[C@H](O1)C2=CC=CC=C2

Technology Process of (2R,3S)-2-Phenyl-3-(propan-2-yl)oxirane

There total 9 articles about (2R,3S)-2-Phenyl-3-(propan-2-yl)oxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15325-61-8,1608-28-2,15325-56-1
(E)-(3-methylbut-1-en-1-yl)benzene

: 582-62-7
3-methyl-1-phenylbutan-1-one

: 2893-05-2
3-methyl-1-phenylbutan-2-one

: 2439-44-3
3-methyl-2-phenylbutanal

: 94719-34-3
cis 2-(1-methylethyl)-3-phenyloxirane

: 94719-35-4
trans 2-(1-methylethyl)-3-phenyloxirane

Guidance literature:: With oxygen; In neat (no solvent); at -25 ℃; for 1.5h; Product distribution; Mechanism; Irradiation; other aryl- and alkyl- subst. ethylene deriv.; var. temp. and reaction times, var. O(³P) sources;
DOI:10.1021/jo00379a013

Reference yield:

: 15325-61-8,1608-28-2,15325-56-1
(E)-(3-methylbut-1-en-1-yl)benzene

: 65473-81-6,94719-34-3,94719-35-4
(2S,3S)-2-isopropyl-3-phenyloxirane

Guidance literature:: With Di(2-ethylhexyl)phthalate; at 30 ℃; for 24h; pH=6.5; optical yield given as %ee; enantioselective reaction; aq. phosphate buffer;
DOI:10.1016/j.tetasy.2010.12.022

Reference yield:

: 119547-81-8
methyl (phenylmethyl)<(trimethylsilyl)methyl>sulfonium trifluoromethanesulfonate

: 78-84-2
isobutyraldehyde

: 94719-34-3
cis 2-(1-methylethyl)-3-phenyloxirane

: 94719-35-4
trans 2-(1-methylethyl)-3-phenyloxirane

Guidance literature:: With cesium fluoride; In 1,2-dimethoxyethane; at 40 ℃; for 12h; Yield given. Yields of byproduct given;
DOI:10.1016/S0040-4020(01)86662-X