119547-81-8

Basic information

• Product Name: methyl (phenylmethyl)<(trimethylsilyl)methyl>sulfonium trifluoromethanesulfonate
• Synonyms: methyl (phenylmethyl)<(trimethylsilyl)methyl>sulfonium trifluoromethanesulfonate
• CAS NO: 119547-81-8
• Molecular Weight: 374.521
• Mol File: 119547-81-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (phenylmethyl)<(trimethylsilyl)methyl>sulfonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (phenylmethyl)<(trimethylsilyl)methyl>sulfonium trifluoromethanesulfonate(119547-81-8)
• EPA Substance Registry System: methyl (phenylmethyl)<(trimethylsilyl)methyl>sulfonium trifluoromethanesulfonate(119547-81-8)

Safety Data

• Hazardous Substances Data: 119547-81-8(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 17988-38-4 trimethyl<<(phenyl)methyl>thiomethyl>silane 
• 333-27-7 methyl trifluoromethanesulfonate 

Downstream Products

• 53226-67-8 trans-2-phenyl-3-[(E)-2-phenyl-1-ethenyl] oxirane 
• 94719-34-3 cis 2-(1-methylethyl)-3-phenyloxirane 
• 94719-35-4 trans 2-(1-methylethyl)-3-phenyloxirane 
• 5925-79-1 1-methyl-2-<(methylthio)methyl>benzene 
• 1439-07-2 trans-Stilbene oxide 
• 22440-35-3 trans-2-(4-methylbenzenyl)-3-phenyl-oxirane 
• 23361-51-5 2-((2S*,3R*)-3-phenyloxiran-2-yl)furan 

Relevant articles and documents

GENERATION OF SULFUR YLIDES BY THE DESILYLATION OF α-TRIMETHYLSILYLBENZYL SULFONIUM SALTS

The -sigmatropic rearrangement of sulfur ylides derived via the desilylation of several α-trimethylsilylbenzyl sulfonium salts has been studied.The initally formed ylide was found to rapidly equilibrate with the thermodynamically more stable ylide.In the absence of trapping reagents, a Sommelet-Hauser type rearrangement occurs.