1,2-DIPHENYLETHANE-D14

Base Information

• Chemical Name: 1,2-DIPHENYLETHANE-D14
• CAS No.: 94371-89-8
• Molecular Formula: C14D14
• Molecular Weight: 196.154
• Mol file: 94371-89-8.mol

Synonyms:Bibenzyl-d14

Chemical Property of 1,2-DIPHENYLETHANE-D14

Chemical Property:

• PSA: 0.00000
• LogP: 3.47180

Purity/Quality:

99%min ^*data from raw suppliers

1,2-Diphenylethane-d14 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1,2-Diphenylethane-d14 is the deuterated form of 1,2-Diphenylethane and can be used in the formation of Toluene-d8

Technology Process of 1,2-DIPHENYLETHANE-D14

There total 11 articles about 1,2-DIPHENYLETHANE-D14 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 2.7%

benzophenone (119-61-9) + (2)H8-toluene (2037-26-5) → 1,1-Diphenylmethanol (91-01-0) + tetraphenylethane-1,2-diol (464-72-2) + benzyl alcohol-d7 (71258-23-6) + diphenylethane-d14 (94371-89-8) + C20H11(2)H7O

Guidance literature:

Quantum yield; Product distribution; Ambient temperature; Irradiation; variation of irradiation time, wavelength, and hydrogen donating solvent;

DOI:10.1021/ja00210a035

Reference yield:

1,3-di(phenyl-d5)-2-propan-d4-one (84752-07-8) → benzyl chloride-d7 (59502-05-5) + diphenylethane-d14 (94371-89-8)

Guidance literature:

With cetyltrimethylammonium chloride; copper dichloride; In water; Quantum yield; Irradiation; cage effect under variety conditions;

DOI:10.1021/ja00345a031

Reference yield:

benzophenone (119-61-9) + (2)H8-toluene (2037-26-5) + toluene (108-88-3,15644-74-3,16713-13-6) → diphenylethane-d14 (94371-89-8) + 1,1'-(1,2-ethanediyl)bisbenzene (103-29-7)

Guidance literature:

at 25 ℃; Thermodynamic data; Kinetics; Irradiation; temperature ranges from -78 to 150 deg C, E_a, k_H/D;

DOI:10.1021/j100172a033

upstream raw materials:

benzophenone

⁽²⁾H₈-toluene

1,3-di(phenyl-d5)-2-propan-d4-one

toluene

Refernces

• 1、 Johnston, Linda J.,Lougnot, D. J.,Wintgens, Veronique,Scaiano, J. C.. "Photochemistry of Diphenylketyl Radicals: Spectroscopy, Kinetics, and Mechanisms". . p. 518 - 524. Retrieved 2007/10/02.