trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate

Base Information

• Chemical Name: trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate
• CAS No.: 676491-68-2
• Molecular Formula: BF₄*C₄₄H₃₆ClN₄P₂Pd
• Molecular Weight: 911.422
• Mol file: 676491-68-2.mol

Synonyms:trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate

Chemical Property of trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate

There total 1 articles about trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.3%

bis-triphenylphosphine-palladium(II) chloride (13965-03-2) + silver tetrafluoroborate (14104-20-2) + 1-(azidomethyl)-2-isocyanobenzene (496963-67-8) → trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate (676491-68-2)

Guidance literature:

In dichloromethane; acetone; byproducts: AgCl; under N2; 1 M soln. of AgBF4 in acetone added to a suspn. of Pd-complex in CH2Cl2 at room temp., stirred for 30 min., AgCl filtered off, filtrate treated with isonitrile, stirred for 2.5 h; Et2O added, ppt. filtered off, dried under vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2003.10.029

Reference yield: 87.9%

trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate (676491-68-2) → trans-chlorobis(triphenylphosphine)(C8H8N2)palladium tetrafluoroborate (676491-73-9)

Guidance literature:

With triphenyl phosphine; In dichloromethane; byproducts: N2, triphenyl phosphinoxide; under N2; PPh3 added to soln. of Pd-complex, stirred at room temp. for 12 h; Et2O added, ppt. filtered off, washed with Et2O, dried in vacuo; elem. anal.;

DOI:10.1016/j.jorganchem.2003.10.029

upstream raw materials:

bis-triphenylphosphine-palladium(II) chloride

silver tetrafluoroborate

1-(azidomethyl)-2-isocyanobenzene

Downstream raw materials:

trans-chlorobis(triphenylphosphine)(C₈H₈N₂)palladium tetrafluoroborate

Refernces