Rhenium,pentacarbonyl(triphenylstannyl)-

Base Information

• Chemical Name: Rhenium,pentacarbonyl(triphenylstannyl)-
• CAS No.: 15614-21-8
• Molecular Formula: C23H15 O5 Re Sn
• Molecular Weight: 676.286
• Mol file: 15614-21-8.mol

Synonyms:Rhenium,pentacarbonyl(triphenylstannyl)-;Rhenium, pentacarbonyl(triphenylstannyl)-;Rhenium,pentacarbonyl(triphenylstannyl)-(OC-6-22)-;15614-21-8

Chemical Property of Rhenium,pentacarbonyl(triphenylstannyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 3
• Exact Mass: 677.94990
• Heavy Atom Count: 30
• Complexity: 407

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)C3=CC=CC=C3.[Re]

Technology Process of Rhenium,pentacarbonyl(triphenylstannyl)-

There total 6 articles about Rhenium,pentacarbonyl(triphenylstannyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

Li(1+)*ReMn(CO)9(CHO)(1-)=Li(ReMn(CO)9(CHO)) (85283-42-7) + triphenyltin chloride (639-58-7) → decacarbonylmanganeserhenium (14693-30-2) + (CO)5ReSn(C6H5)3 (15614-21-8) + triphenyltinmanganesepentacarbonyl (14405-84-6)

Guidance literature:

In tetrahydrofuran; under N2, soln. of Re-Mn-complex in THF was stirred for 5 h at room temp., cooled to -78°C, Ph3SnCl was added, warmed to room temp.; solvent removed by rotary evapn., chromd. on silica gel with ethyl acetate-hexane, solvent removed by rotary evapn., sublimed at 50°C, residue dissolved in hot hexane, placed in freezer overnight;

Reference yield:

Li[cis-Re2(CO)9(CHO)]*tetrahydrofuran + triphenyltin chloride (639-58-7) → decacarbonyldirhenium(0) (14285-68-8) + (CO)5ReSn(C6H5)3 (15614-21-8)

Guidance literature:

In neat (no solvent); under N2, Re-compelx was evacuated, heated in 94-95°C oil bath, cooled, 1 equiv of Ph3SnCl in THF was added, stirred for 1 h; detected by silica gel TLC;

Reference yield:

decacarbonyldirhenium(0) (14285-68-8) + triphenyltin chloride (639-58-7) → (CO)5ReSn(C6H5)3 (15614-21-8)

Guidance literature:

With sodium amalgam; In tetrahydrofuran; Ar, Na/Hg added to a soln. of Re-compound, after 2 h excess Na/Hg removed, Ph3SnCl in THF added stirred for 2 days; solvent removed, triturated with toluene, evapd. to dryness, recrystd. from ether and isooctane;

DOI:10.1021/ja00547a012

upstream raw materials:

(CO)5ReYbBr

triphenyltin chloride

(CO)5ReYbCl

(CO)5ReYbI

Downstream raw materials:

Re(CO)4{Sn(C₆H₅)3}{Sb(C₆H₅)3}